199338-66-4

Upstream product

• 32384-42-2 (1S,3R,4S,5R)-3,4-O-isopropylidene-1,5-quinic lactone 
• 98-59-9 p-toluenesulfonyl chloride 
• 199338-64-2 [(3aS,4aR,7aR,8R,8aS)-8-(tert-Butyl-dimethyl-silanyloxy)-2,2,6,6-tetramethyl-tetrahydro-benzo[1,2-d;4,5-d']bis[1,3]dioxol-3a-yl]-methanol 
• 199338-50-6 (3aR,5R,6S,7S,7aR)-7-(tert-Butyl-dimethyl-silanyloxy)-5,6-dihydroxy-2,2-dimethyl-hexahydro-benzo[1,3]dioxole-5-carboxylic acid methyl ester 
• 199338-51-7 (3aR,4aR,7aR,8R,8aS)-8-(tert-Butyl-dimethyl-silanyloxy)-2,2,6,6-tetramethyl-tetrahydro-benzo[1,2-d;4,5-d']bis[1,3]dioxole-3a-carboxylic acid methyl ester 
• 199338-49-3 (3aR,7S,7aR)-7-(tert-Butyl-dimethyl-silanyloxy)-2,2-dimethyl-3a,4,7,7a-tetrahydro-benzo[1,3]dioxole-5-carboxylic acid methyl ester 
• 160080-76-2 (3aR,7S,7aS)-7-Hydroxy-2,2-dimethyl-3a,4,7,7a-tetrahydro-benzo[1,3]dioxole-5-carboxylic acid methyl ester 
• 97373-88-1 methyl (1R,3R,4S,5R)-1,5-dihydroxy-3,4-(isopropylidenedioxy)cyclohexane-1-carboxylate 
• 97205-16-8 methyl 4,5-O-isopropylidene-3-dehydro-4-epi-shikimate 
• 77-95-2 D-(-)-quinic acid 
• 98-88-4 benzoyl chloride 

Downstream Products

• 205932-30-5 Benzoic acid (3aS,4aR,7aS,8R,8aS)-8-hydroxy-2,2,6,6-tetramethyl-tetrahydro-benzo[1,2-d;4,5-d']bis[1,3]dioxol-3a-ylmethyl ester 

Relevant academic research and scientific papers

Catalytic asymmetric epoxidation

A compound and method for producing an enantiomerically enriched epoxide from an olefin using a chiral ketone and an oxidizing agent is disclosed.

A Class of C2 and Pseudo C2 Symmetric Ketone Catalysts for Asymmetric Epoxidation. Conformational Effect on Catalysis

A class of C2 and pseudo C2 symmetric ketones with one fused ring at each side of the carbonyl group have been prepared from quinic acid and found to be effective catalysts for the asymmetric epoxidation of a variety of olefins. Electron deficient olefins such as enones can be efficiently epoxidized. Encouragingly good enantioselectivity is also obtained for the epoxidation of styrenes. The studies show that the ketone conformation plays an important role in the reactivity and selectivity of the catalyst.