199532-88-2

Basic information

• Product Name: 3-Cyclopentene-1-carboxylicacid,1-amino-,ethylester(9CI)
• Synonyms: 3-Cyclopentene-1-carboxylicacid,1-amino-,ethylester(9CI);ethyl 1-aminocyclopent-3-enecarboxylate
• CAS NO: 199532-88-2
• Molecular Formula: C₈H₁₃NO₂
• Molecular Weight: 155.19
• Product Categories: CARBOXYLICESTER;GLYCINESCAFFOLD
• Mol File: 199532-88-2.mol
• Article Data: 7

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-Cyclopentene-1-carboxylicacid,1-amino-,ethylester(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Cyclopentene-1-carboxylicacid,1-amino-,ethylester(9CI)(199532-88-2)
• EPA Substance Registry System: 3-Cyclopentene-1-carboxylicacid,1-amino-,ethylester(9CI)(199532-88-2)

Safety Data

• Hazardous Substances Data: 199532-88-2(Hazardous Substances Data)

Upstream product

• 64-17-5 ethanol 
• 199532-83-7 ethyl 1-((4-bromobenzylidene)amino)cyclopent-3-ene-1-carboxylate 
• 952193-55-4 (2R)-5,5-diallyl-3,6-diethoxy-2,5-dihydro-2-isopropylpyrazine 
• 952193-54-3 (2R,5S)-5-allyl-3,6-diethoxy-2,5-dihydro-2-isopropylpyrazine 
• 952193-59-8 C₁₅H₂₄N₂O₂ 
• 1953-56-6 (Z)-but-2-ene-1,4-diyl dimethanesulfonate 
• 76910-08-2 cyclopent-3-ene-1,1-dicarboxylic acid ethyl ester 
• 76910-09-3 ethyl 1-(chloroformyl)cyclopent-3-ene-1-carboxylate 
• 21622-00-4 Cyclopent-3-ene-1,1-dicarboxylic acid diethyl ester 

Downstream Products

• 199532-89-3 1-(3-Phenyl-ureido)-cyclopent-3-enecarboxylic acid ethyl ester 
• 1310415-39-4 C₁₄H₁₅NO₄S 
• 1310417-87-8 C₁₄H₁₅NO₅S 
• 1310415-41-8 C₁₇H₂₃NO₅SSi 
• 1310415-42-9 1-tosyl-3-oxa-1-azaspiro[4.4]non-8-ene-2,7-dione 
• 1310415-43-0 C₂₀H₂₇NO₅SSi 

Relevant articles and documents

Diastereoselective Solid-Phase Synthesis of Novel Hydantoin- and Isoxazoline-Containing Heterocycles

Exploiting 1,3-dipolar cycloaddition and carbanilide cyclization transformations, we have prepared novel spirocyclic isoxazoloimidazolidinedione heterocycles of generalized structures II and III on solid phase starting from Merrifield resin. Cyclopentanoid isoxazoloimidazolidinedione II was obtained with complete diastereoselectivity, and cyclopropanoid isoxazoloimidazolidinedione III was obtained as an ≈ 2:1 mixture of diastereomers.

Complete facial selectivity in the Diels-Alder reaction of a 5-amino-5-carboxycyclopentadiene derivative

5-tert-Butoxycarbonylamino-5-carbethoxy-2-tert-butyldimethylsilyloxy- cyclopentadiene undergoes a Diels-Alder reaction exclusively from the face syn to the nitrogen functionality. Complete reversal of facial bias may be achieved, but at the cost of dimini

Regio- and diastereoselective synthesis of cyclic amino esters

Several cyclic amino esters have been prepared regio- and diastereoselectively depending on the electrophile (cis or trans alkene) and its leaving group.