199661-51-3

Upstream product

• 1040132-12-4 (R,E)-5-(tert-butyldiphenylsilyloxy)-2-methylpent-2-ene-1,4-diol 
• 147200-08-6 (3S,5R)-5-(tert-butyldiphenylsilyloxymethyl)-3-methyl-dihydrofuran-2(3H)-one 

Downstream Products

• 199661-52-4 Benzoic acid (2S,4R)-5-(tert-butyl-diphenyl-silanyloxy)-4-hydroxy-2-methyl-pentyl ester 
• 199661-54-6 Benzoic acid (2S,4R)-5-hydroxy-4-(2-methoxy-ethoxymethoxy)-2-methyl-pentyl ester 
• 199661-56-8 Benzoic acid (2S,4R)-5-azido-4-(2-methoxy-ethoxymethoxy)-2-methyl-pentyl ester 
• 199661-58-0 Toluene-4-sulfonic acid (2S,4R)-5-azido-4-(2-methoxy-ethoxymethoxy)-2-methyl-pentyl ester 
• 199661-55-7 Benzoic acid (2S,4R)-4-(2-methoxy-ethoxymethoxy)-2-methyl-5-(toluene-4-sulfonyloxy)-pentyl ester 
• 199661-53-5 Benzoic acid (2S,4R)-5-(tert-butyl-diphenyl-silanyloxy)-4-(2-methoxy-ethoxymethoxy)-2-methyl-pentyl ester 

Relevant academic research and scientific papers

Asymmetric hydrogenation approaches to valuable, acyclic 1,3-hydroxymethyl chirons

An iridium carbene oxazoline complex was used to catalyze hydrogenations of trisubstituted alkenes to give terminal and internal 1,3-hydroxymethyl chirons. The products are accessible in all possible stereoisomeric forms. These hydrogenations do not requi

Total synthesis of zoanthamine alkaloids, part 2. Construction of the C1-C5, C6-C10, and C11-C24 fragments of zoanthamine

This paper describes the construction of three key intermediates 11, 15 and 23 for a projected total synthesis of the marine alkaloid zoanthamine. These building blocks, corresponding to the C1-C5, C6-C10, and C