2000-88-6

Basic information

• Product Name: Benzoic acid, 2,4,6-trimethyl-, 2-propenyl ester
• CAS NO: 2000-88-6
• Molecular Formula: C13H16O2
• Molecular Weight: 204.269
• Mol File: 2000-88-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 2,4,6-trimethyl-, 2-propenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 2,4,6-trimethyl-, 2-propenyl ester(2000-88-6)
• EPA Substance Registry System: Benzoic acid, 2,4,6-trimethyl-, 2-propenyl ester(2000-88-6)

Safety Data

• Hazardous Substances Data: 2000-88-6(Hazardous Substances Data)

Upstream product

• 480-63-7 mesitylenecarboxylic acid 
• 107-18-6 allyl alcohol 
• 106-95-6 allyl bromide 
• 938-18-1 mesitylene-2-carboxylic acid chloride 

Downstream Products

• 300-57-2 allylbenzene 
• 480-63-7 mesitylenecarboxylic acid 
• 123-38-6 propionaldehyde 
• 15561-17-8 1-mesityl-but-2-en-1-one 
• 3982-67-0 ethylmesitylene 
• 36971-09-2 (E)-1-mesitylbut-2-en-1-one 

Relevant articles and documents

Atmospheric Oxygen Mediated Radical Hydrothiolation of Alkenes

A mild, metal-free, atmospheric oxygen-mediated radical hydrothiolation of alkenes (and alkyne) is reported. A variety of sulfur containing motifs including alkanethiols, thiophenols and thioacids undergo an atmospheric oxygen-mediated radical hydrothiolation reaction with a plethora of alkenes in good yield with excellent functional group compatibility, typically with short reaction times to furnish a range of functionalized products. Biomolecules proved tolerant to the conditions and the procedure is robust and easily executable requiring no specialized equipment. Concise mechanistic studies confirm the process proceeds through radical intermediates in a thiol-ene reaction manifold. The methodology offers an efficient “green” approach for thiol-ene mediated “click” ligation and a milder alternative to thermally initiated hydrothiolation processes.

Efficient in situ esterification of carboxylic acids using cesium carbonate

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