200001-79-2Relevant academic research and scientific papers
A joint experimental and computational investigation on homoconjugated push-pull chromophores derived from 7,7-diphenylnorbornane
Herrero-Garcia, Noelia,Del Rosario Colorado Heras, Maria,Del Rosario Torres, Maria,Fernandez, Israel,Osio Barcina, Jose
supporting information; experimental part, p. 2643 - 2655 (2012/06/04)
We report hereon the synthesis, spectroscopic properties and computational studies of novel aromatic homoconjugated compounds derived from 7,7-diphenylnorbornane (DPN). The UV/Vis spectra of these compounds show bands corresponding to the respective chrom
Hindered rotation in diphenylmethane derivatives. Electrostatic vs charge-transfer and homoconjugative aryl-aryl interactions
Martínez, A. García,Osío Barcina,De Fresno Cerezo,Gutiérrez Rivas
, p. 673 - 679 (2007/10/03)
A series of p,p'-disubstituted 7-phenyl-7-(2-fluorophenyl)norbornanes 5xy has been prepared, and the barrier (ΔG#) to 160°libration around the 2-fluoroaryl-norbornane bond has been measured by DNMR. There is spectroscopic evidence of strong homoconjugativ
