20005-32-7

Basic information

• Product Name: Tetrahydro-2-furanacetaldehyde
• Synonyms: Tetrahydro-2-furanacetaldehyde;2-(tetrahydrofuran-2-yl)acetaldehyde
• CAS NO: 20005-32-7
• Molecular Formula: C₆H₁₀O₂
• Molecular Weight: 114.1424
• Mol File: 20005-32-7.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Tetrahydro-2-furanacetaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: Tetrahydro-2-furanacetaldehyde(20005-32-7)
• EPA Substance Registry System: Tetrahydro-2-furanacetaldehyde(20005-32-7)

Safety Data

• Hazardous Substances Data: 20005-32-7(Hazardous Substances Data)

Usage

Uses

Tetrahydro-2-furanacetaldehyde is used in reactions involving methyl nucelophiles. A reagent used in the preparation of stereospecific compounds.

Upstream product

• 109-99-9 tetrahydrofuran 
• 85684-59-9 percarbonate de O,O-t-butyle et O-vinyle 

Downstream Products

• 1312018-29-3 1-(1-benzenesulfonyl-5-methoxy-1H-pyrrolo[2,3-b]pyridin-2-yl)-2-(tetrahydro-furan-2-yl)-ethanol 
• 1312019-35-4 1-benzenesulfonyl-2-[1-(4-methanesulfonyl-phenyl)-2-(tetrahydro-furan-2-yl)-vinyl]-1H-pyrrolo[2,3-b]pyridine 
• 1312019-34-3 toluene-4-sulfonic acid 1-(1-benzenesulfonyl-1H-pyrrolo[2,3-b]pyridin-2-yl)-2-(tetrahydro-furan-2-yl)-vinyl ester 
• 1312019-36-5 (Z)-2-[1-(4-methanesulfonyl-phenyl)-2-(tetrahydro-furan-2-yl)-vinyl]-1H-pyrrolo[2,3-b]pyridine 
• 1312019-33-2 1-(1-benzenesulfonyl-1H-pyrrolo[2,3-b]pyridin-2-yl)-2-(tetrahydro-furan-2-yl)-ethanone 
• 1312017-03-0 2-[1-(4-methanesulfonyl-phenyl)-2-(tetrahydro-furan-2-yl)-ethyl]-1H-pyrrolo[2,3-b]pyridine 
• 1312017-02-9 (E)-2-[1-(4-methanesulfonyl-phenyl)-2-(tetrahydro-furan-2-yl)-vinyl]-1H-pyrrolo[2,3-b]pyridine 
• 1312019-32-1 1-(1-benzenesulfonyl-1H-pyrrolo[2,3-b]pyridin-2-yl)-2-(tetrahydro-furan-2-yl)-ethanol 

Relevant articles and documents

Obtention d'aldehydes γ-fonctionnels au cours de la thermolyse du percarbonate de O,O-t-butyle et O-vinyle en solution

Owing to its peroxyester group, O,O-tert-butyl and O-vinyle peroxycarbonate may act as a free radical initiator in solution, but also, due to the presence of the vinylic insaturation, as a substrate for free radical addition reactions. - In such solvents as cumene which give free radicals unable to add to the double bond, the peroxycarbonate merely behaves as a vinyloxy radicals generator.It is thus possible to observe these radicals reacting either as formylmethyl radicals or as acetyl radicals. - In solvents such as cyclohexane which give free radicals able to add to the double bond, the reaction results in the substitution of formylmethyl groups to labile hydrogens of the solvent. - By applying the reaction to such compounds as ketones, ethers, acids and their derivatives, we could obtain γ-functional aldehydes (γ-ketoaldehydes, γ-oxaaldehydes and derivatives of succinaldehydic acids).These products are often difficult to prepare by other routes and until now only some of them have been described.