200068-36-6

Usage

Uses

Used in Optoelectronic Applications:
2,5-dibromo-1,1,3,4-tetraphenylsilole is used as a luminescent material for optoelectronic devices due to its enhanced electron and hole mobility. This property allows for improved performance in devices such as organic light-emitting diodes (OLEDs) and organic photovoltaics (OPVs), where efficient charge transport is crucial.
Used in Chemical Sensing:
2,5-dibromo-1,1,3,4-tetraphenylsilole is used as a sensing material in chemical sensors for detecting various analytes. Its luminescent properties enable the development of sensors with high sensitivity and selectivity, making it a promising candidate for environmental monitoring and safety applications.
Used in Materials Science:
In the field of materials science, 2,5-dibromo-1,1,3,4-tetraphenylsilole is used as a building block for the synthesis of novel conjugated materials. Its unique structure and properties can be exploited to create materials with tailored electronic, optical, and structural characteristics for a wide range of applications, including advanced electronic devices and energy storage systems.
Used in Research and Development:
2,5-dibromo-1,1,3,4-tetraphenylsilole is also used as a research compound in the development of new materials and technologies. Its unique properties make it an interesting subject for scientific investigation, potentially leading to the discovery of new applications and advancements in various fields.

Upstream product

• 18784-61-7 1,1-diphenylbis(phenylethynyl)silane 

Downstream Products

• 200068-38-8 2-Bromo-1,1,3,4-tetraphenyl-5-trimethylsilanyl-1H-silole 
• 200068-39-9 2-Dimethylsilanyl-1,1,3,4-tetraphenyl-5-trimethylsilanyl-1H-silole 

Relevant academic research and scientific papers

Synthesis of 1,1-Diisopropyl- or -Diphenyl -2,5-dibromo- or -bis(trimethylsilyl)-3,4-diphenyl-siloles and the Electrochemical Properties as Anode Materials for Lithium-Ion Battery

Intramolecular cyclization of 1,1-diisopropyl- or diphenyl-bis(phenylethynyl)-silanes (2a and 2b) followed by bromination or trimethylsilylation were carried out to yield 1,1-diisopropyl- or -diphenyl-3,4-diphenyl-2,5-dibromo-siloles (3a and 3b) and 1,1-d

Synthesis, structure, aggregation-induced emission, self-assembly, and electron mobility of 2,5-bis(triphenylsilylethynyl)-3,4-diphenylsiloles

2,5-Bis(triphenylsilylethynyl)-3,4-diphenylsiloles with different 1,1-substituents [XYSi(CPh)2(C-C≡C-SiPh3) 2] (Ph=phenyl) were synthesized in high yields by the Sonogashira coupling of 2,5-dibromo-3,4-diphenylsiloles with triphenylsilylacetylene, and two of these were characterized crystallographically. Crystal structures and theoretical calculations showed that the new silole molecules had higher conjugation than 2,5-diarylsiloles. They possessed low HOMO and LUMO energy levels due to the electron-withdrawing effect of the triphenylsilylethynyl groups. Cyclic voltammetry analysis revealed low electron affinities, which were comparable to those of perfluoroarylsiloles. B3LYP/6-31* calculations demonstrated that the new siloles possessed large reorganization energies for electron and hole transfers and high electron mobilities. A mobility of up to 1.2 × 10-5 cm2V-1s-1 was obtained by the transient electroluminescence method, which was about fivefold higher than that of tris(8-hydroxyquinolinato)aluminum, a widely used electron-transport material, under the same conditions. All of the silole molecules possessed high thermal stability. Although, their solutions were weakly emissive, their nanoparticle suspensions and thin films emitted intense blue-green light upon photoexcitation, demonstrating a novel feature of aggregation-induced emission (AIE). Polarized emissions were observed in the silole crystals. The addition of solvents, which did not dissolve the silole molecules, into silole-containing solutions caused self-assembly of the molecules, which produced macroscopic fibrils with strong light emissions. Copyright