18784-61-7

Usage

Uses

Used in Chemical Synthesis:
Silane, diphenylbis(phenylethynyl)is used as a reactant in the synthesis of deep blue fluorescent 2,5-bis(phenylsilyl)-substituted 3,4-diphenylsiloles. This application takes advantage of the compound's unique structure and reactivity, allowing for the creation of novel materials with specific optical properties.
In the Chemical Industry:
Silane, diphenylbis(phenylethynyl)is used as a building block for the development of new materials with potential applications in various fields, such as electronics, optics, and pharmaceuticals. Its unique structure and reactivity make it a valuable component in the synthesis of complex organic molecules and advanced materials.
In the Research and Development Sector:
Silane, diphenylbis(phenylethynyl)is also utilized in research and development, where it can be employed to study the properties and behavior of silicon-containing molecules. Understanding the characteristics of diphenylbis(phenylethynyl)silane can contribute to the advancement of knowledge in the field of organosilicon chemistry and potentially lead to the discovery of new applications and uses for Silane, diphenylbis(phenylethynyl)-.

Upstream product

• 80-10-4 diphenylsilyl dichloride 
• 4440-01-1 lithium phenylacetylide 
• 63378-81-4 diphenyldiiodosilane 
• 536-74-3 phenylacetylene 
• 775-12-2 diphenylsilane 

Downstream Products

• 886-66-8 1,4-diphenyl-1,3-butadiyne 
• 163223-90-3 1,1,4-Triphenyl-2-[1-phenyl-meth-(Z)-ylidene]-1,2-dihydro-silete 
• 886-65-7 trans,trans-1,4-Diphenyl-1,3-butadiene 
• 163237-36-3 Zr(C₅H₅)2(C₆H₅)2(C₆H₅)2SiC₄ 
• 1239590-77-2 (diphenyl)(phenylethinyl)(silicon)C(CHC₆H₅)bis(tert-butyl)aluminum 
• 120776-55-8 1-(2,3,5,6-tetrafluoropyridyl)-2-phenylethyne 
• 370-99-0 4-trifluoromethyldiphenylethyne 
• 405-29-8 (4-fluorophenyl)phenylacetylene 
• 891203-09-1 C₂₈H₂₀Cl₂SiZn₂ 
• 1616777-47-9 2,5-bis(4-(dimesitylboryl)phenyl)-1,1,3,4-tetraphenylsilole 
• 928846-96-2 1,1,3,4-tetraphenyl-2,5-bis(9,9-dimethylfluoren-2-yl)-silole 
• 198826-60-7 Zr(C₅H₄(C₄H₉))2(C₆H₅)2(C₆H₅)2SiC₄ 

Relevant academic research and scientific papers

Synthesis and characterization of poly(silole-pyridine)

New poly(silole-pyridine) was designed and synthesized. Polymer was obtained by Yamamoto coupling reaction. The structure of obtained polymer was characterized by the spectroscopic methods such as FT-IR and 1H-NMR. The resulting polymer was sol

Synthesis and characterization of new poly(silole-fluorene) copolymers

New poly(silole-fluorene) copolymers were designed and synthesized. Copolymers were obtained by Suzuki coupling reaction with different ratio of fluorene and silole. The obtained copolymers were characterized by the spectroscopic methods such as FT-IR and

Synthesis and cure kinetics of diphenyl(diphenylethynyl)silane monomer

Diphenyl(diphenylethynyl)silane ((ph-C≡C)2-Si-ph 2) (DPDPES) was synthesized by the Grignard reaction. The corresponding isothermal and non-isothermal cure kinetics of DPDPES were analyzed by using differential scanning calorimetry (

Synthesis of 1,1-Diisopropyl- or -Diphenyl -2,5-dibromo- or -bis(trimethylsilyl)-3,4-diphenyl-siloles and the Electrochemical Properties as Anode Materials for Lithium-Ion Battery

Intramolecular cyclization of 1,1-diisopropyl- or diphenyl-bis(phenylethynyl)-silanes (2a and 2b) followed by bromination or trimethylsilylation were carried out to yield 1,1-diisopropyl- or -diphenyl-3,4-diphenyl-2,5-dibromo-siloles (3a and 3b) and 1,1-d

Role of C, S, Se and P donor ligands in copper(i) mediated C-N and C-Si bond formation reactions

The first comparative study of C, S, Se and P donor ligands-supported copper(i) complexes for C-N and C-Si bond formation reactions are described. The syntheses and characterization of eight mononuclear copper(i) chalcogenone complexes, two polynuclear co

One-pot desilylation-Sonogashira coupling

Coupling of diethynyldiphenylsilane (1) with aryl halides under Sonogashira conditions affords the symmetrical diarylacetylenes bis(2-methylpyridin-5-yl)acetylene (2), bis(4-fluorophenyl)acetylene (3) and bis(4-trifluoromethylphenyl) acetylene (4) in 60% to 82% yield. In the case of 2, the by-product bis(2-methylpyridin-5-yl)butadiyne (2a) was isolated in 12% yield. The occurring desilylation reaction was investigated by treating bis(phenylethynyl)diphenylsilane (5) under the same conditions. The formation of 1-fluoro-4-(phenylethynyl)benzene (6), 1-trifluoromethyl- 4-(phenylethynyl)benzene (7) and (tetrafluoropyridin- 4-yl)ethynylbenzene (8) in 70 to 84% yield and the cleavage of hexaphenylcyclotrisiloxane were observed in all cases.

A new and efficient route for the synthesis of alkynyl functionalized silicon derivatives

The iridium-based catalytic system, [{Ir(μ-Cl)(CO)2} 2]/NEt(i-Pr)2, was examined in the coupling reaction of iodotrisubstituted silanes (R3SiI) with various terminal arylalkynes (R1CCH). Under optimum

Iridium-promoted conversion of chlorosilanes to alkynyl derivatives in a one-pot reaction sequence

By making use of the catalytic potential of the iridium system [{Ir(μ-Cl)(CO)2}2]/NEt(i-Pr)2 in the synthesis of silyl-functionalized alkynes via silylative coupling of terminal alkynes/diynes with iodosilanes, we propose

Dehydrogenative coupling between hydrosilanes and alkynes catalyzed by alkoxides, alkylmetals, and metalamides

The selective dehydrogenative coupling reaction between phenylsilane and ethynylbenzene occurred in the presence of some homogeneous base catalysts such as alkoxides, alkyl compounds, and the amides of alkali metals or barium. The order of the catalytic activities was Ba(OR)2 > LiN(SiMe3)2 ～ n -BuLi > LiOEt. Barium alkoxide showed the highest activity and selectivity for the reaction, and gave the polymer poly[(phenylsilylene)ethynylene-1,3-phenyleneethynylene] in the reaction of phenylsilane with m-diethynylbenzene. The correlation between the catalytic activities and the catalyst basicities was discussed, and a reaction mechanism involving both the metal acetylide and the metal hydride was proposed.

Copper(I) chloride catalyzed cross-dehydrocoupling reactions between silanes and ethynyl compounds. A new method for the copolymerization of silanes and alkynes

In the presence of an amine, copper(I) chloride is an effective catalyst for the cross-dehydrocoupling of silanes with alkynes.The reactions proceed at useful rates above 100 deg C, but rates drop dramatically on going from 1o to 2o