200272-75-9

Upstream product

• 3396-99-4 methyl α-D-galactopyranoside 
• 200272-67-9 methyl 3,4-O-cyclohexylidene-α-D-galactopyranoside 
• 933-40-4 cycloxexanone dimethyl ketal 
• 100-39-0 benzyl bromide 
• 200272-70-4 methyl 6-bromo-3,4-O-cyclohexylidene-6-deoxy-α-D-galactopyranoside 

Relevant academic research and scientific papers

Stereoselective synthesis of 6-deoxy and 3,6-dideoxy-D-myo-inositol precursors of deoxy-myo-inositol phosphate analogues from D-galactose

The synthesis of chiral protected D-6-deoxy-myo-inositol derivatives from D-galactose is described. Ferrier rearrangement of hexenogalactopyranosides has been employed to produce the corresponding 6- deoxy-cyclohexanone polyols. The stereoselectivity of the carbocyclic transformation was discussed on the basis of the experimental data and a mechanism has been proposed. From deoxy-inososes, the access to a variety of 6-deoxy and 3,6-dideoxy-myo-inositol was performed to prepare suitable monool, diol and triol precursors for the synthesis of D-deoxy-myo-inositol phosphate analogues.