20089-20-7Relevant articles and documents
Reductive Difunctionalization of Aryl Alkenes with Sodium Metal and Reduction-Resistant Alkoxy-Substituted Electrophiles
Fukazawa, Mizuki,Nogi, Keisuke,Sasamori, Takahiro,Takahashi, Fumiya,Yorimitsu, Hideki
supporting information, (2020/03/13)
A general method for alkali-metal-promoted reductive difunctionalization of alkenes has been developed by means of reduction-resistant alkoxy-substituted electrophiles. A series of 1,2-diboration and 1,2-dicarbofunctionalization products can be synthesize
Enantioselective preparation of a novel chiral 1,2-diamine
Demay, Stéphane,Kotschy, Andras,Knochel, Paul
, p. 863 - 866 (2007/10/03)
A short enantioselective preparation of (1S,2S)-trans-1,2-diamino-3-cyclohexene using a double [3,3]-sigmatropic rearrangement of an allylic bis(imidate) is described (Overman rearrangement). The starting chiral diol is conveniently obtained by enzymatic resolution.
SYNTHESIS OF A SIMPLE MODEL OF THE CARCINOGENIC EPOXYDIOLS AND INVESTIGATION OF ITS MUTAGENIC ACTIVITY
Berti, Giancarlo,Mastrorilli, Ettore,Bronzetti, Giorgio
, p. 449 - 452 (2007/10/02)
Whereas epoxidation of trans-3-cyclohexene-1,2-diol with MCPBA is highly stereospecific, yielding the anti and syn epoxides in a ratio of 98:2, the corresponding dibenzoate gives the anti-epoxide in low yield, since the more reactive syn-epoxide decompose
