88230-04-0

Basic information

• Product Name: (+/-)-trans-1,2-Diacetoxy-3-cyclohexene
• Synonyms: (+/-)-trans-1,2-Diacetoxy-3-cyclohexene
• CAS NO: 88230-04-0
• Molecular Weight: 198.219
• Mol File: 88230-04-0.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: (+/-)-trans-1,2-Diacetoxy-3-cyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-trans-1,2-Diacetoxy-3-cyclohexene(88230-04-0)
• EPA Substance Registry System: (+/-)-trans-1,2-Diacetoxy-3-cyclohexene(88230-04-0)

Safety Data

• Hazardous Substances Data: 88230-04-0(Hazardous Substances Data)

Upstream product

• 2570-63-0 thallium(III) triacetate 
• 1165952-91-9 cyclohexa-1,3-diene 
• 110-83-8 cyclohexene 
• 20089-20-7 (+/-)-trans-1,2-Dihydroxy-3-cyclohexene 
• 108-24-7 acetic anhydride 
• 64-19-7 acetic acid 
• 76644-52-5 rac-3-acetoxycyclohexene 
• 546-67-8 lead(IV) tetraacetate 

Downstream Products

• 91210-43-4 C₂₂H₄₂O₄Si₂ 
• 91210-42-3 (3S,4R)-3,4-Bis-[1-(tert-butyl-dimethyl-silanyloxy)-vinyloxy]-cyclohexene 
• 28981-66-0 (+/-)-3,4-dideoxyconduritol D 
• 674309-47-8 (1R,2R)-2-hydroxycyclohex-3-en-1-yl acetate 
• 351902-64-2 (S,S)-trans-1,2-Diacetoxy-3-cyclohexene 
• 674309-47-8 Acetic acid (1S,2S)-2-hydroxy-cyclohex-3-enyl ester 
• 88270-75-1 (1R,2R)-trans-cyclohex-3-en-1,2-diol 
• 351464-36-3 (1S,2S)-trans-3-cyclohexene-1,2-diol 

Relevant articles and documents

New C2-symmetrical 1,2-diphosphanes for the efficient rhodium-catalyzed asymmetric hydroboration of styrene derivatives

A double [2,3] sigmatropic rearrangement enables the fast synthesis of novel C2-symmetrical 1,2-diphosphanes in good yields. These phosphanes (for example, 1; c-Hex = cyclohexyl) are highly efficient ligands for the rhodium-catalyzed asymmetric hydroboration of a wide variety of styrenes (see scheme). cod = 1,5-cyclooctadiene; DME = 1,2-dimethoxyethane.

Hydroxyhalogenations of acyloxycyclohex-2-enes. Part 3. Iterative 1,2-hydroxyiodination of acetoxycyclohex-2-ene: Preparation of tetraacetyl conduritol D

Compound 22, the tetraacetyl derivative of conduritol D, has been synthesized by repeated hydroxyiodination reactions in nine steps from acetoxycyclohex-2-ene.

Diastereospecific Hydroxyiodination of 1-Acetoxycyclohex-2-ene via Intramolecular Delivery of Oxygen

The previously unreported reaction of N-iodosuccinimide with acetoxycyclohex-2-ene to give monoacetates of 3-iodocyclohexane-1,2-diols is diastereospecific.