201053-15-8Relevant academic research and scientific papers
Synthesis and structure of the first 2H-1,3,2-diazaphosphole complex
Wilkens, Hendrik,Jeske, Joerg,Jones, Peter G.,Streubel, Rainer
, p. 2317 - 2318 (1997)
Thermal decomposition of the 2H-azaphosphirene tungsten complex 1 in benzonitrile and in the presence of dimethylcyanamide yields the 2H-1,3,2-diazaphosphole tungsten complex 4, containing a novel five-membered heterocyclic ligand; the overall reaction may be described as a 1,3-dipolar cycloaddition of an in situ generated nitrilium phosphane ylide complex to benzonitrile.
First synthesis and structures of 2H-1,3,2-diazaphosphole tungsten complexes
Wilkens, Hendrik,Streubel, Rainer
, p. 83 - 92 (2007/10/03)
Thermal decomposition of a 2H-azaphosphirene tungsten complex in the presence of various nitrile derivatives yielded 2H-1,3,2-diazaphosphole tungsten complexes. The overall reaction may be described as a 1,3-dipolar cycloaddition of an in situ generated n
