1467-79-4Relevant articles and documents
Tris(3,5-dimethylpyrazolyl)methane copper(I) complexes featuring one disubstituted cyanamide ligand
Melekhova, Anna A.,Novikov, Alexander S.,Dubovtsev, Alexey Yu.,Zolotarev, Andrey A.,Bokach, Nadezhda A.
, p. 69 - 74 (2019)
The complexes [Cu{HC(3,5-Me2pz)3}(NCNR2)][BF4] (1–8; R2 = Me2 1, Et2 2, C5H10 3, C4H8O 4, C4H8 5, C3H
Accelerated degradation of methyl iodide by agrochemicals
Zheng, Wei,Papiernik, Sharon K.,Guo, Mingxin,Yates, Scott R.
, p. 673 - 679 (2003)
The fumigant methyl iodide (Mel, iodomethane) is considered a promising alternative to methyl bromide (MeBr) for soil-borne pest control in high-cash-value crops. However, the high vapor pressure of Mel results in emissions of a significant proportion of the applied mass into the ambient air, and this may lead to pollution of the environment. Integrating the application of certain agrochemicals with soil fumigation provides a novel approach to reduce excessive fumigant. emissions. This study investigated the potential for several agrochemicals that are commonly used in farming operations, including fertilizers and nitrification inhibitors, to transform Mel in aqueous solution. The pseudo-first-order hydrolysis half-life (t1/2) of Mel was ～ 108 d, while the transformation of Mel in aqueous solutions containing selected agrochemicals was more rapid, with t1/2 1/2 1/2 of Mel was 1/2 > 300 h).
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Weingarten
, p. 293 (1966)
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Selenium-nitrogen bond formation by ring expansion: Synthesis of the 1,4,2-diselenazine ring system, fragmentation to a 1,2-diselenete and reactions to yield 1,4-diselenin derivatives
Yoshida, Shimon,Bryce, Martin R.,Chesney, Antony
, p. 2375 - 2376 (1996)
1,3-Diselenolium cation salt 1 reacts with ammonia and iodine to afford the novel 1,4,2-diselenazine system 6 (40% yield) which fragments to yield dimethylcyanamide 8 and diselenin 9, presumably via intermediate 1,2-diselenete 7, which is trapped with dimethyl acetylenedicarboxylate to yield the cycloadduct 10.
A allyl uncle amine compound by one-step synthesis method of cyano uncle amine compound (by machine translation)
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Paragraph 0052-0060, (2017/09/01)
The invention relates to a one-step synthesis of amine compound allyl unclecyano uncle amine compounds, which belongs to the technical field of organic synthetic method. The method specific synthetic process is as follows: in the airtight reaction environment, to the anhydrous organic solvent is added in the cyanogen bromide, under protection of inert gas, and then added dropwise to the solution in the allylic and high yield amine compound, to obtain allyl uncle amine compound concentration is 0.8 - 1 mol/L solution, at room temperature the reaction 16 - 24 hours later, after column chromatography separation and purification, to obtain a corresponding cyano uncle amine compound. The method to get rid of the expensive deallylation use of the catalyst, the synthesis step is less, raw materials are easy, cheap, mild reaction conditions, the operation is simple, easy to craft and industrialization. Yield 50% - 80% between. (by machine translation)
Novel and facile transformation of N,N-disubstituted glycylamides into corresponding cyanamides by using pentavalent iodine reagents in combination with tetraethylammonium bromide
Chaudhari, Kiran H.,Mahajan, Ulhas S.,Bhalerao, Dinesh S.,Akamanchi, Krishnacharya G.
, p. 2815 - 2818 (2008/02/12)
Novel and facile transformation of N,N-disubstituted glycylamides into corresponding cyanamides using pentavalent iodine reagents and tetraethylammonium bromide is discussed. The advantages of this system are use of non toxic reagents, shorter reaction times and moderate to good yields. Georg Thieme Verlag Stuttgart.
