201151-77-1Relevant academic research and scientific papers
F--induced decomposition of 3-[(tert-Butyldimethylsiloxy)phenoxy]-3-phenyl-1,2- dioxetanes without C-C bond cleavage of the dioxetane ring
Matsumoto, Masakatsu,Azami, Mitsunori
, p. 8947 - 8950 (1997)
F--induced decomposition of 3-[3-tert-butyldimethylsiloxy)phenoxy]-3-phenyl-1,2- dioxetane (5c) yielded an intramolecular redox product (7b), whereas 3-phenoxy-3-(3-siloxyphenyl)-1,2-dioxetane (3) gave normal carbonyl fragments with intense light emission. An isomer (5a) gave light with normal decomposition by CIEEL, though the major process was one to yield an acyloin (7a).
