Tetrahedron Letters p. 8947 - 8950 (1997)
Update date:2022-08-05
Topics:
Matsumoto, Masakatsu
Azami, Mitsunori
F--induced decomposition of 3-[3-tert-butyldimethylsiloxy)phenoxy]-3-phenyl-1,2- dioxetane (5c) yielded an intramolecular redox product (7b), whereas 3-phenoxy-3-(3-siloxyphenyl)-1,2-dioxetane (3) gave normal carbonyl fragments with intense light emission. An isomer (5a) gave light with normal decomposition by CIEEL, though the major process was one to yield an acyloin (7a).
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