F--induced decomposition of 3-[(tert-Butyldimethylsiloxy)phenoxy]-3-phenyl-1,2- dioxetanes without C-C bond cleavage of the dioxetane ring

DOI: 10.1016/S0040-4039(97)10359-8

Source and publish data:

Tetrahedron Letters p. 8947 - 8950 (1997)

Update date:2022-08-05

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Authors:

Matsumoto, Masakatsu

Azami, Mitsunori

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Article abstract of DOI:10.1016/S0040-4039(97)10359-8

F^--induced decomposition of 3-[3-tert-butyldimethylsiloxy)phenoxy]-3-phenyl-1,2- dioxetane (5c) yielded an intramolecular redox product (7b), whereas 3-phenoxy-3-(3-siloxyphenyl)-1,2-dioxetane (3) gave normal carbonyl fragments with intense light emission. An isomer (5a) gave light with normal decomposition by CIEEL, though the major process was one to yield an acyloin (7a).

Full text of DOI:10.1016/S0040-4039(97)10359-8

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