20117-74-2Relevant academic research and scientific papers
VINYL MIGRATION IN THE OXYTHALLATION OF SOME 1,3-DIENES
Murakami, Masashi,Nishida, Shinya
, p. 997 - 1000 (2007/10/02)
The oxythallation of certain 1,3-dienes with thallium (III) nitrate trihydrate in MeOH-CH2Cl2 at 0-20 deg C gave products after vinyl migration .Methyl 1-methylcyclopropyl ketone, obtained in the reaction of 2,3-dimethyl-1,3-butadiene, was presumably derived from a cyclopropylmethyl cation, an intermediate in the vinyl migration.
