201209-93-0

Basic information

• Product Name: (+)-2-(3-benzyloxypropyl)-2-methylcyclohexanone
• Synonyms: (+)-2-(3-benzyloxypropyl)-2-methylcyclohexanone
• CAS NO: 201209-93-0
• Molecular Weight: 260.376
• Mol File: 201209-93-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (+)-2-(3-benzyloxypropyl)-2-methylcyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-2-(3-benzyloxypropyl)-2-methylcyclohexanone(201209-93-0)
• EPA Substance Registry System: (+)-2-(3-benzyloxypropyl)-2-methylcyclohexanone(201209-93-0)

Safety Data

• Hazardous Substances Data: 201209-93-0(Hazardous Substances Data)

Upstream product

• 7770-41-4 1-methyl-2-oxocyclohexanecarboxylic acid 2-propenyl ester 
• 91906-66-0 pimelic acid diallyl ester 
• 111-16-0 heptanedioic acid 
• 201210-07-3 2-(3-hydroxypropyl)-2-methylcyclohexanol 
• 53068-89-6 (R)-(+)-2-(2'-carbomethoxyethyl)-2-methylcyclohexanone 
• 211234-68-3 [6-(3-Benzyloxy-propyl)-bicyclo[4.1.0]hept-1-yloxy]-trimethyl-silane 
• 211234-57-0 [2-(3-Benzyloxy-propyl)-cyclohex-1-enyloxy]-trimethyl-silane 
• 184366-55-0 2-(3-(benzyloxy)propyl)cyclohexanone 
• 211234-83-2 Chloro-acetic acid 6-(3-benzyloxy-propyl)-bicyclo[4.1.0]hept-1-yl ester 
• 201210-08-4 (R)-2-(3-Benzyloxy-propyl)-2-methyl-cyclohexanol 
• 10424-93-8 N'-cyclohexylidene-N,N-dimethyl-hydrazine 

Relevant articles and documents

Total Synthesis of the Alleged Structure of Crenarchaeol Enables Structure Revision**

Crenarchaeol is a glycerol dialkyl glycerol tetraether lipid produced exclusively in Archaea of the phylum Thaumarchaeota. This membrane-spanning lipid is undoubtedly the structurally most sophisticated of all known archaeal lipids and an iconic molecule in organic geochemistry. The 66-membered macrocycle possesses a unique chemical structure featuring 22 mostly remote stereocenters, and a cyclohexane ring connected by a single bond to a cyclopentane ring. Herein we report the first total synthesis of the proposed structure of crenarchaeol. Comparison with natural crenarchaeol allowed us to propose a revised structure of crenarchaeol, wherein one of the 22 stereocenters is inverted.

Enzymatic resolution of bicyclo[n.1.0]alkan-1-ols derivatives: Preparation of optically active α-substituted α-methylcycloalkanones

Optically active α-methyl α-substituted cycloalkanones are prepared by a chemoenzymatic sequence which involves a Lipozyme-catalyzed transesterification of 1-(chloroacetoxy)bicyclo[n.1.0]alkanes and ring opening of these cyclopropanol derivatives.