201210-64-2

Upstream product

• 55628-54-1 3,4,6-tri-O-benzyl-D-glucal 
• 604767-65-9 Phosphoric acid (4R,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-3-hydroxy-tetrahydro-pyran-2-yl ester dibutyl ester 
• 1011723-04-8 glucal epoxide 
• 75-08-1 ethanethiol 
• 226919-69-3 dibutyl 3,4,6-tri-O-benzyl-2-O-triethylsilyl-β-D-glucopyranoside phosphate 
• 226919-79-5 dibutyl 2-O-pivaloyl-3,4,6-tri-O-benzyl-α-D-glucopyranoside phosphate 
• 226919-62-6 dibenzyl 2-O-pivaloyl-3,4,6-tri-O-benzyl-β-D-glucopyranoside phosphate 

Relevant academic research and scientific papers

Oligosaccharide synthesis with glycosyl phosphate and dithiophosphate triesters as glycosylating agents

Described is an efficient one-pot synthesis of α- and β-glycosyl phosphate and dithiophosphate triesters from glycals via 1,2-anhydrosugars. Glycosyl phosphates function as versatile glycosylating agents for the synthesis of β-glucosidic, β-galactosidic,

Synthesis and use of glycosyl phosphates as glycosyl donors.

Differentially protected glycosyl phosphates prepared by a straightforward synthesis from glycal precursors are used as powerful glycosyl donors. Activation of beta-glycosyl phosphates by TMSOTf at -78 degrees C achieves the selective formation of beta-gl