604767-65-9

Upstream product

• 107-66-4 dibutyl phosphate 
• 1011723-04-8 glucal epoxide 
• 55628-54-1 3,4,6-tri-O-benzyl-D-glucal 

Downstream Products

• 226919-69-3 dibutyl 3,4,6-tri-O-benzyl-2-O-triethylsilyl-β-D-glucopyranoside phosphate 
• 226919-63-7 dibutyl 2-O-pivaloyl-3,4,6-tri-O-benzyl-β-D-glucopyranoside phosphate 
• 226919-79-5 dibutyl 2-O-pivaloyl-3,4,6-tri-O-benzyl-α-D-glucopyranoside phosphate 
• 226919-73-9 thioethyl 2-O-pivaloyl-3,4,6-tri-O-benzyl-β-D-glucopyranoside-(1->6)-3,4-di-O-benzyl-2-O-pivaloyl-β-D-mannopyranoside 
• 201210-64-2 ethyl 3,4,6-tri-O-benzyl-2-O-pivaloyl-1-thio-β-D-glucopyranoside 
• 40246-33-1 3,4,6-tri-O-benzyl-β-D-glucopyranoside-(1->6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranoside 

Relevant academic research and scientific papers

Synthesis and use of glycosyl phosphates as glycosyl donors.

Differentially protected glycosyl phosphates prepared by a straightforward synthesis from glycal precursors are used as powerful glycosyl donors. Activation of beta-glycosyl phosphates by TMSOTf at -78 degrees C achieves the selective formation of beta-gl

Methyltrioxorhenium catalyzed domino epoxidation-nucleophilic ring opening of glycals

The use of catalytic methylrhenium trioxide (MTO) and urea hydrogen peroxide in room temperature ionic liquid for the hydroxyglycosylation with glycals in a domino fashion is reported. Excellent conversions and good selectivities for the epoxidation reaction were observed. Application to the synthesis of glycosylphosphates, good glycosyl donors, has been studied.