201345-80-4Relevant academic research and scientific papers
Electrophilic fluorodesilylation of allenylmethylsilanes: A novel entry to 2-fluoro-1,3-dienes
Pacheco, Ma. Carmen,Gouverneur, Veronique
, p. 1267 - 1270 (2007/10/03)
(Chemical Equation Presented) Various fluorodienes were prepared by treatment of the corresponding allenylmethylsilanes with Selectfluor. This is the first route to these compounds not based on the use of a fluorinated building block. The reaction allows
Preparation of 2-iodo-1,3-butadienes from 1-trimethylsilyl-2,3- butadienes and their functionalizations
Nishiyama, Takashi,Esumi, Tomoyuki,Iwabuchi, Yoshiharu,Irie, Hiroshi,Hatakeyama, Susumi
, p. 43 - 46 (2007/10/03)
Successive treatment of 1-trimethylsilyl-2.3-butadienes with iodine and tetra-n-butylammonium fluoride in the same flask affords 2-iodo-1.3- butadienes in good yields and their palladium-catalyzed carbonylation and alkynylation allows introduction of este
