201355-16-0Relevant academic research and scientific papers
Studies in marine macrolide synthesis: Synthesis of a C16-C28 subunit of spongistatin 1 (altohyrtin A) incorporating the CD-spisoacetal moiety
Paterson, Ian,Wallace, Debra J.,Gibson, Karl R.
, p. 8911 - 8914 (1997)
The C16-C28 ketone 3, containing the CD-spiroacetal of spongistatin 1 (1), was prepared in 17 steps from aldehyde 9. Both thermodynamic and kinetic conditions were explored for controlling the CD-acetal configuration.
