Studies in marine macrolide synthesis: Synthesis of a C16-C28 subunit of spongistatin 1 (altohyrtin A) incorporating the CD-spisoacetal moiety

DOI: 10.1016/S0040-4039(97)10483-X

Source and publish data:

Tetrahedron Letters p. 8911 - 8914 (1997)

Update date:2022-08-04

Topics:

Authors:

Paterson, Ian

Wallace, Debra J.

Gibson, Karl R.

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Article abstract of DOI:10.1016/S0040-4039(97)10483-X

The C₁₆-C₂₈ ketone 3, containing the CD-spiroacetal of spongistatin 1 (1), was prepared in 17 steps from aldehyde 9. Both thermodynamic and kinetic conditions were explored for controlling the CD-acetal configuration.

Full text of DOI:10.1016/S0040-4039(97)10483-X

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