201405-92-7Relevant academic research and scientific papers
Electroorganic synthesis of benzathine
Lateef, Shaik,Reddy Krishna Mohan, Srinivasulu,Reddy Jayarama Reddy, Srinivasulu
, p. 77 - 80 (2007/10/03)
Benzathine is prepared in good yields from cyanobenzene by a combination of electrochemical hydrogenation and Kolbe electrolysis using nickel and platinum electrodes in the presence of methanolic sodium methoxide in an undivided cell.
Convenient synthesis of 4-trifluoromethyl-substituted imidazole derivatives
Kawase,Saito,Kurihara
, p. 461 - 464 (2007/10/03)
Mesoionic 4-trifluoroacetyl-1,3-oxazolium-5-olates (1), obtained from the reaction of N-acyl-N-alkylglycines (2) with trifluoroacetic anhydride, react with ammonia to give 4-trifluoromethyl-3,4-dihydroimidazoles (3) in high yields. Dehydration of 3 gives
The Alkylation of Menthyl Hippurate and Some Related Materials: A Reinvestigation.
McIntosh, John M.,Thangarasa, Rasiah,Foley, Nancy K.,Ager, David J.,Froen, Diane E.,Klix, Russell C.
, p. 1967 - 1974 (2007/10/02)
Benzylation of chiral esters of N-acyglycines using various bases and additives was examined.No C-alkylation was observed with one equivalent of base.Diastereoselectivities were dependent on the amount of additive, the nature of the N-acyl group, and the chiral ester.A model to account for the degree and sense of the stereoselectivity is proposed.
