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20152-34-5

Silane, (1,1-dimethylethyl)dimethyl[(6-methyl-1-cyclohexen-1-yl)oxy]- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 20152-34-5 Structure

  • Basic information

    1. Product Name: Silane, (1,1-dimethylethyl)dimethyl[(6-methyl-1-cyclohexen-1-yl)oxy]-
    2. Synonyms: 1-tert-butyldimethylsilyloxy-6-methyl-1-cyclohexene;
    3. CAS NO:20152-34-5
    4. Molecular Formula: C13H26OSi
    5. Molecular Weight: 226.434
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 20152-34-5.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 223.1±8.0 °C(Predicted)
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: 0.86±0.1 g/cm3(Predicted)
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Silane, (1,1-dimethylethyl)dimethyl[(6-methyl-1-cyclohexen-1-yl)oxy]-(CAS DataBase Reference)
    10. NIST Chemistry Reference: Silane, (1,1-dimethylethyl)dimethyl[(6-methyl-1-cyclohexen-1-yl)oxy]-(20152-34-5)
    11. EPA Substance Registry System: Silane, (1,1-dimethylethyl)dimethyl[(6-methyl-1-cyclohexen-1-yl)oxy]-(20152-34-5)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 20152-34-5(Hazardous Substances Data)

20152-34-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 20152-34-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,0,1,5 and 2 respectively; the second part has 2 digits, 3 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 20152-34:
(7*2)+(6*0)+(5*1)+(4*5)+(3*2)+(2*3)+(1*4)=55
55 % 10 = 5
So 20152-34-5 is a valid CAS Registry Number.

20152-34-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name tert-butyl-dimethyl-(6-methylcyclohexen-1-yl)oxysilane

1.2 Other means of identification

Product number -
Other names 1-tert-butyldimethylsilyloxy-6-methyl-1-cyclohexene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:20152-34-5 SDS

20152-34-5Relevant articles and documents

Facile isomerization of silyl enol ethers catalyzed by triflic imide and its application to one-pot isomerization-(2 + 2) cycloaddition

Inanaga, Kazato,Ogawa, Yu,Nagamoto, Yuuki,Daigaku, Akihiro,Tokuyama, Hidetoshi,Takemoto, Yoshiji,Takasu, Kiyosei

supporting information; experimental part, p. 658 - 661 (2012/06/01)

A triflic imide (Tf2NH) catalyzed isomerization of kinetically favourable silyl enol ethers into thermodynamically stable ones was developed. We also demonstrated a one-pot catalytic reaction consisting of (2 + 2) cycloaddition and isomerization. In the reaction sequence, Tf2NH catalyzes both of the reactions.

N-heterocyclic carbene-catalyzed silyl enol ether formation

Song, Jinhua J.,Tan, Zhulin,Reeves, Jonathan T.,Fandrick, Daniel R.,Yee, Nathan K.,Senanayake, Chris H.

supporting information; experimental part, p. 877 - 880 (2009/04/07)

N-Heterocyclic carbenes (NHCs) were found to catalyze the silyl transfer from trialkylsilyl ketene acetals to ketones. In the presence of a catalytic amount of NHC 3 (IAd, 0.1 to 5 mol%), a series of enolizable ketones as well as cyclohexanecarboxaldehyde

Lewis acid-catalyzed nucleophilic substitutions of propargylic and allylic silyl ethers with enol silyl ethers

Ishikawa, Teruhiko,Aikawa, Toshiaki,Mori, Yumiko,Saito, Seiki

, p. 51 - 54 (2007/10/03)

(Matrix presented) Nucleophilic reactions of various enol silyl ethers with carbocation species generated from propargyl silyl ethers by the action of a Lewis acid have been developed. The present method is highly useful for the introduction of allenic or

Silazanes/catalytic bases: Mild, powerful and chemoselective agents for the preparation of enol silyl ethers from ketones and aldehydes

Tanabe, Yoo,Misaki, Tomonori,Kurihara, Minoru,Iida, Akira,Nishii, Yoshinori

, p. 1628 - 1629 (2007/10/03)

We have developed an efficient method for the preparation of enol silyl ethers using novel agents, silazanes together with NaH or DBU catalyst, wherein TMS and TBDMS groups were smoothly and chemoselectively introduced into ketones and aldehydes under mil

SYNTHESIS OF t-BUTYLDIMETHYLSILYL ENOL ETHERS FROM STERICALLY HINDERED KETONES

Mander, Lewis N.,Sethi, S. Paul

, p. 5953 - 5956 (2007/10/02)

Ketones react rapidly with t-butyldimethylsilyl triflate and amine bases to form t-butyldimethylsilyl enol ethers in high yield.

PREPARATION OF TERT-BUTYLDIMETHYLSILYL (TBDMS) ENOL ETHERS USING POTASSIUM HYDRIDE IN THE PRESENCE OF TBDMS CHLORIDE

Orban, John,Turner, John V.,Twitchin, Bruce

, p. 5099 - 5102 (2007/10/02)

TBDMS enol ethers can be readily prepared regio- and stereoselectively under equilibrating conditions in high yield by adding potassium hydride to a THF solution of ketone with TBDMS chloride in situ.

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