201683-52-5

Upstream product

• 547-63-7 Methyl isobutyrate 
• 671207-31-1 (S)-4-benzyl-3-[(S)-6-benzyloxy-2-methyl-hexanoyl]-oxazolidin-2-one 
• 201683-50-3 (E)-(S)-8-Benzyloxy-2,4-dimethyl-oct-2-en-1-ol 
• 201683-51-4 [(2S,3S)-3-((S)-5-Benzyloxy-1-methyl-pentyl)-2-methyl-oxiranyl]-methanol 
• 188729-96-6 (S)-6-Benzyloxy-2-methyl-hexanal 
• 188729-97-7 (S)-6-benzyloxy-2-methyl-1-hexanol 
• 143761-23-3 (+)-4S-3-[1'-oxo-6'-(benzyloxy)hexyl]-4-benzyl-2-oxazolidinone 

Downstream Products

• 201683-59-2 (3S,6R,7S,8S)-12-Benzyloxy-7-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-4,4,6,8-tetramethyl-5-oxo-dodecanoic acid tert-butyl ester 
• 201683-57-0 (4R,5S,6S)-10-Benzyloxy-1,5-bis-(tert-butyl-dimethyl-silanyloxy)-2,2,4,6-tetramethyl-decan-3-one 
• 201683-56-9 1-[(2R,3S)-3-((S)-5-Benzyloxy-1-methyl-pentyl)-2-methyl-oxiranyl]-3-(tert-butyl-dimethyl-silanyloxy)-2,2-dimethyl-propan-1-one 
• 1026479-66-2 (4R,5S,6S)-10-Benzyloxy-1-(tert-butyl-dimethyl-silanyloxy)-5-hydroxy-2,2,4,6-tetramethyl-decan-3-one 
• 201683-58-1 (4R,5S,6S)-10-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-1-hydroxy-2,2,4,6-tetramethyl-decan-3-one 
• 201683-53-6 1-[(2S,3S)-3-((S)-5-Benzyloxy-1-methyl-pentyl)-2-methyl-oxiranyl]-3-(tert-butyl-dimethyl-silanyloxy)-2,2-dimethyl-propan-1-ol 

Relevant academic research and scientific papers

Radical-induced opening of trisubstituted epoxides: Application in the synthesis of C1-C12 segment of epothilones

Diastereo- and regioselective opening of a trisubstituted epoxy ketone at the more substituted carbon using samarium(II) iodide presents an alternate approach to the C5-C7 aldol moiety with β-hydroxyketo framework in the stereoselective synthesis of C1-C12 segment of epothilones.