20172-42-3

Basic information

• Product Name: N-benzylidenedodecylamine
• Synonyms: N-benzylidenedodecylamine;N-Benzylidene-N-dodecylamine;Einecs 243-560-3
• CAS NO: 20172-42-3
• Molecular Formula: C₁₉H₃₁N
• Molecular Weight: 273.45614
• EINECS: 243-560-3
• Mol File: 20172-42-3.mol
• Article Data: 14

Chemical Properties

• Boiling Point: 377.5°Cat760mmHg
• Flash Point: 174.5°C
• Appearance: /
• Density: 0.87g/cm³
• Vapor Pressure: 1.46E-05mmHg at 25°C
• Refractive Index: 1.488
• PKA: 5.54±0.50(Predicted)
• CAS DataBase Reference: N-benzylidenedodecylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzylidenedodecylamine(20172-42-3)
• EPA Substance Registry System: N-benzylidenedodecylamine(20172-42-3)

Safety Data

• Hazardous Substances Data: 20172-42-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C19H31N/c1-2-3-4-5-6-7-8-9-10-14-17-20-18-19-15-12-11-13-16-19/h11-13,15-16,18H,2-10,14,17H2,1H3/b20-18+

Upstream product

• 124-22-1 n-Dodecylamine 
• 100-52-7 benzaldehyde 
• 100-46-9 benzylamine 
• 100-51-6 benzyl alcohol 

Downstream Products

• 1687-68-9 dodecylbenzylamine 
• 7311-30-0 N-methyldodecylamine 
• 20477-66-1 (α-dodecylaminobenzyl)phosphonic acid 
• 260396-67-6 carboxyisobutyl α-dodecylaminobenzylphosphonic acid monoester 
• 1239346-04-3 C₂₆H₃₈N⁽¹⁺⁾*Cl^(1-) 
• 221631-14-7 3-(benzyl-dodecyl-amino)-propionic acid 
• 651320-50-2 (2R,3R)-2-[(Dodecylamino-phenyl-methyl)-hydroxy-phosphinoyloxy]-3-hydroxy-succinic acid dibutyl ester 
• 1558953-52-8 1-(N-(N^α,N^ε-di-Boc-Lys)-N-dodecylamino)methylbenzene 
• 2090-62-2 N-dodecyl-1-aminomethylbenzene hydrochloride 
• 261965-58-6 5-(dodecylamino-phenyl-methyl)-3,3,8,8-tetramethyl-1,4,6,9-tetraoxa-5λ⁵-phospha-spiro[4.4]nonane-2,7-dione 

Relevant articles and documents

Asymmetric synthesis of (α-amino)phosphonic acid amphiphiles using chiral P-H spirophosphoranes

Chiral P-H spirophosphoranes reacted with long-chain prochiral aldimines and, after selective hydrolysis, afforded (α-amino)phosphonic acid amphiphiles in both enantiopure forms.

Molybdenum Nitride Nanocatalyst Derived from Melamine and Polyoxometalate-based Hybrid for Oxidative Coupling of Amines to Imines with Air

Molybdenum nitride (Mo2N) is one of the most promising alternative catalysts for a wide range of Pt-catalyzed catalytic applications but is seldom investigated in oxidative coupling of amines to imines. A Mo2N-based nanocatalyst is successfully achieved by the hybridization of PMo12O403? (PMo)-paired ionic pyridine-4-carboxylic acid (PC) and melamine (Mel), followed by calcination in N2. Melamine acts as an outstanding carburization and nitridation reagent that can convert into carbon nitride, and meanwhile the released N element react with Mo species in PMo to form Mo2N. The obtained catalyst PC-PMo-Mel-800 exhibits high activity and remarkable stability for the oxidative coupling of amines to imines under solvent-free and atmospheric conditions. This is the first case of Mo2N-catalyzed oxidative coupling reaction catalyst. The strategy reported herein for fabricating Mo2N may provide a significant and interesting approach to design more transition metal nitrides for wide catalytic applications.

Ligand-Controlled Inversion of Diastereo- and Enantioselectivity in Silver-Catalyzed Azomethine Ylide-Imine Cycloaddition of Glycine Aldimino Esters with Imines

A highly diastereo- and enantioselective silver-catalyzed azomethine ylide-imine (AYI) cycloaddition reaction of glycine aldimino esters with imines was developed in which the Xing-Phos-controlled syn-selective or DTBM-Segphos-induced anti-selective AYI cycloaddition reaction could be applied to the synthesis of a variety of stereodivergent 1-alkyl-2,5-substituted imidazolidines with high yields and excellent enantioselectivities (up to 99% ee) as well as good diastereoselectivities (up to 99:1 dr) under mild reaction conditions.