201732-49-2

Basic information

• Product Name: C₃₈H₃₄NO₂P
• CAS NO: 201732-49-2
• Molecular Weight: 567.667
• Mol File: 201732-49-2.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 730.0±70.0 °C(Predicted)
• CAS DataBase Reference: C₃₈H₃₄NO₂P(CAS DataBase Reference)
• NIST Chemistry Reference: C₃₈H₃₄NO₂P(201732-49-2)
• EPA Substance Registry System: C₃₈H₃₄NO₂P(201732-49-2)

Safety Data

• Hazardous Substances Data: 201732-49-2(Hazardous Substances Data)

Usage

General Description

C38H34NO2P is a chemical compound consisting of 38 carbon atoms, 34 hydrogen atoms, one nitrogen atom, one oxygen atom, and one phosphorus atom. It is classified as an organic compound and its molecular formula suggests that it contains a large number of carbon and hydrogen atoms, potentially indicating a complex structure. The presence of nitrogen, oxygen, and phosphorus suggests that it may have biological or physiological properties, as these elements are commonly found in biomolecules. The exact nature and properties of this compound would depend on its specific structure and functional groups, which would need to be determined through further chemical analysis and investigation.

Upstream product

• 21003-56-5 (1S,1'S)-bis(1-phenylethyl)amine 
• 39648-71-0 3,3’-dimethyl-[1,1’-binaphthalene]-2,2’-diol 
• 55442-34-7 3,3'-dimethyl-1,1'-binaphthalene-2,2'-diol 
• 10024-74-5 (R,R)-N,N-bis-(1-phenylethyl)amine 
• 777067-26-2 [(R,R)-bis(α-methylbenzyl)amino]phosphorous dichloride 

Relevant articles and documents

First synthesis of a beta(2)-homoamino acid by enantioselective catalysis.

The enantioselective conjugate addition of diethylzinc to the activated nitroolefin methyl 3-nitropropenoate is efficiently catalyzed by copper(I) complexes with BINOL-based enantiopure phosphoramidite ligands. The nitroolefin moiety acts as the predomina

Conjugate Addition of Organozinc Compounds to Nitroolefins

Symmetrical (R2Zn) or mixed diorganozinc compounds (R 1ZnR2) smoothly react with a series of nitroolefins in the presence of catalytic amounts of copper(I) salts and provide synthetically versatile nitro compounds in moderate to good yields. Simple alkyl groups, functionalized residues, or mixed trimethylsilylmethyl organozinc compounds (TMSM)ZnR may be employed for conjugate addition, while the TMSM group is not being transferred. ipso-Substitution is observed in absence of the copper(I) salt. Enantiomerically pure copper(I) complexes with BINOL based chiral phosphoramidite ligands efficiently catalyze the addition of dialkylzinc compounds to nitroalkenes. For instance, diethylzinc addition occurs with high yields and excellent enantioselectivity. Nitrostyrene, 3-nitroacrolein dimethylacetal, and 3-nitroacrylates have been used as substrates. The nitroolefin moiety predominates over the acrylate moiety and acts as the more powerful Michael acceptor. 2-Alkyl-3-nitropropanoates are exclusively obtained with excellent yield and enantioselectivity. The products can easily be transformed into β2-homoamino acids, compounds of high relevance for different areas of preparative organic chemistry.