201870-82-8

Usage

Uses

Used in Chiral Selector Applications:
(Acetato-κO)[[2,2'-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-κN)Methylidyne]]bis[4,6-bis(1,1-diMethylethyl)phenolato-κO]](2-)]cobalt is used as a chiral selector for PVC membrane electrodes. Its unique structure allows for the selective recognition and separation of enantiomers, which is crucial in various analytical and pharmaceutical applications.
Used in Polymer Industry:
In the polymer industry, (Acetato-κO)[[2,2'-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-κN)Methylidyne]]bis[4,6-bis(1,1-diMethylethyl)phenolato-κO]](2-)]cobalt is used as a highly active catalyst for the copolymerization of propylene oxide and carbon dioxide. This process leads to the formation of polycarbonate materials with improved properties, such as enhanced biodegradability and reduced environmental impact.
Used in Environmental Applications:
(Acetato-κO)[[2,2'-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-κN)Methylidyne]]bis[4,6-bis(1,1-diMethylethyl)phenolato-κO]](2-)]cobalt can also be employed in environmental applications, where its catalytic properties can be utilized for the conversion of carbon dioxide into valuable chemicals and materials, contributing to a more sustainable and eco-friendly approach to chemical production.

Upstream product

• 176763-62-5 (R,R)-(-)-N,N’-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) 
• 64-19-7 acetic acid 
• 672304-10-8 (S,S)-bis(3,5-di-tert-butylsalicylide)-1,2-cyclohexanediamino-Co(II) 

Relevant academic research and scientific papers

Molecular cobalt-salen complexes as novel cocatalysts for highly efficient photocatalytic hydrogen production over a CdS nanorod photosensitizer under visible light

An efficient photocatalytic system is highly demanded for the production of hydrogen fuel through water splitting. Herein, we report an artificial photocatalytic system made of low-cost materials for high-performance H2 production from water. The new system contains semiconductors (CdS nanorods) as the photosensitizer, a cobalt-salen complex as the H2 evolution cocatalyst, and Na2S and Na2SO3 as sacrificial electron donors. Under optimal conditions, the highest hydrogen evolution turnover number reached 64 700 after 37 hours and the rate was 106 μmol h-1 mg-1, which is much higher than when using CdS NRs and also is among the best for photocatalytic systems using molecular cocatalysts for H2 production. The highest apparent quantum yield (AQY) was ～29% at 420 nm. Steady state photoluminescence (PL) spectra and time-resolved photoluminescence (TRPL) decay spectra revealed that the system allows effective electron transfer from the excited CdS NRs to the cobalt-salen complex for highly efficient H2 production.

Stereoselective synthesis of C19-C27 fragment of bryostatin 11

A convergent synthesis of C19-C27 fragment (2) of bryostatin-11 is described. The key steps involved in this approach are kinetic resolution, Grignard reaction, and Sharpless dihydroxylation. AIBN catalyzed radical cyclization strategy has been used for the first time to construct the six-membered pyran system.