201936-63-2Relevant academic research and scientific papers
New approaches to fluorinated ligands and their application in catalysis
Chen, Weiping,Xu, Lijin,Hu, Yulai,Banet Osuna, Anna M,Xiao, Jianliang
, p. 3889 - 3899 (2007/10/03)
Simple and generic approaches to fluorous soluble ligands have been developed and applied to the synthesis of various fluorinated arylphosphines including polymeric ones. The utility of some of these ligands has been demonstrated in catalysis in supercritical CO2 (scCO2) and fluorous solvents.
Phosphorus(III) ligands in fluorous biphase catalysis
Bhattacharyya, Pravat,Croxtall, Ben,Fawcett, Joanne,Fawcett, John,Gudmunsen, David,Hope, Eric G.,Kemmitt, Ray D.W.,Paige, Danny R.,Russell, David R.,Stuart, Alison M.,Wood, Dan R.W.
, p. 247 - 255 (2007/10/03)
The synthesis, coordination chemistry and catalytic applications of a series of perfluoroalkyl-substituted phosphorus(III) ligands is illustrated.
Novel and efficient synthesis of perfluoroalkylated arylphosphines
Chen, Weiping,Xiao, Jianliang
, p. 3697 - 3700 (2007/10/03)
A novel, high-yield route has been developed for the synthesis of perfluoroalkylated arylphosphines, involving simple, copper-mediated coupling of haloarylphosphine oxides with perfluoroalkyl iodides followed by reduction with trichlorosilane. (C) 2000 Elsevier Science Ltd.
Phosphorus(III) ligands with fluorous ponytails
Bhattacharyya, Pravat,Gudmunsen, David,Hope, Eric G.,Kemmitt, Ray D. W.,Paige, Danny R.,Stuart, Alison M.
, p. 3609 - 3612 (2007/10/03)
A series of phosphorus(III) compounds incorporating one or more C6F13 'ponytails' have been prepared as a pool of ligands for coordination and catalytic studies under the fluorous biphase regime. Solubility studies indicate that only ligands with three or more ponytails are preferentially soluble in perfluorocarbon solvents.
