201936-63-2

Basic information

• Product Name: (4-perfluorohexylphenyl)diphenylphosphine
• Synonyms: (4-perfluorohexylphenyl)diphenylphosphine
• CAS NO: 201936-63-2
• Molecular Weight: 580.328
• Mol File: 201936-63-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (4-perfluorohexylphenyl)diphenylphosphine(CAS DataBase Reference)
• NIST Chemistry Reference: (4-perfluorohexylphenyl)diphenylphosphine(201936-63-2)
• EPA Substance Registry System: (4-perfluorohexylphenyl)diphenylphosphine(201936-63-2)

Safety Data

• Hazardous Substances Data: 201936-63-2(Hazardous Substances Data)

Upstream product

• 589-87-7 1,4-bromoiodobenzene 
• 355-43-1 n-perfluorohexyl iodide 
• 5525-40-6 (4-bromophenyl)diphenylphosphine oxide 
• 1079-66-9 chloro-diphenylphosphine 
• 149068-56-4 4-(tridecafluoro-n-hexyl)bromobenzene 

Downstream Products

• 219938-05-3 [RhCl₂(C₅(CH₃)5)(P(C₆H₅)2C₆H₄C₆F₁₃)] 

Relevant articles and documents

New approaches to fluorinated ligands and their application in catalysis

Simple and generic approaches to fluorous soluble ligands have been developed and applied to the synthesis of various fluorinated arylphosphines including polymeric ones. The utility of some of these ligands has been demonstrated in catalysis in supercritical CO2 (scCO2) and fluorous solvents.

Novel and efficient synthesis of perfluoroalkylated arylphosphines

A novel, high-yield route has been developed for the synthesis of perfluoroalkylated arylphosphines, involving simple, copper-mediated coupling of haloarylphosphine oxides with perfluoroalkyl iodides followed by reduction with trichlorosilane. (C) 2000 Elsevier Science Ltd.