20204-06-2Relevant academic research and scientific papers
Polarity-reversal-catalyzed hydrostannylation reactions: Benzeneselenol-mediated homolytic hydrostannylation of electron-rich olefins
Ford, Leigh,Wille, Uta,Schiesser, Carl H.
, p. 2306 - 2311 (2007/10/03)
Addition of 10 mol-% of diphenyl diselenide to hydrostannylation reactions involving electron-rich olefins results in a dramatic improvement in yield. For example, reaction of α-([(tert-butyl)dimethylsilyl]-oxy}styrene (1) with triphenylstannane (2a; 1.1
cis- and trans-(4-alkylcyclohexyl)stannanes. Isomers for stereochemical studies of substitution at saturated carbon-tin bonds
Olszowy, Henry A.,Kitching, William
, p. 1670 - 1675 (2008/10/08)
The synthesis and characterization of pure cis- and trans-(4-methylcyclohexyl)- and cis- and trans-(4-tert-butylcyclohexyl)triphenylstannanes are described. Their conversion, by hydrochloric acid induced dephenylation-isopropylation, to the corresponding triisopropylstannanes proceeds smoothly to provide stereoisomers capable of providing significant information with respect to brominolysis and trifluoroacetolysis of the carbon-tin bond.
