202115-29-5Relevant academic research and scientific papers
Quaternization of the bridgehead nitrogen in silatranylosmium(II) complexes and reestablishment of the transannular N-Si bond following migratory insertion of the silatranyl ligand
Attar-Bashi, Moayad T.,Rickard, Clifton E. F.,Roper, Warren R.,Wright, L. James,Woodgate, Scott D.
, p. 504 - 506 (1998)
The Si-N distance in the five-coordinate silatranyl complex Os(Si{OCH2CH2}3N)Cl(CQ)(PPh3) 2 (1a, Q = O) is very long, and the geometry about nitrogen is planar. Accordingly, the nitrogen atom readily
