20216-92-6Relevant academic research and scientific papers
Non-catalytic conversion of C-F bonds of benzotrifluorides to C-C bonds using organoaluminium reagents
Terao, Jun,Nakamura, Misaki,Kambe, Nobuaki
scheme or table, p. 6011 - 6013 (2010/11/16)
A facile method for the conversion of C-F bonds of benzotrifluorides to C-C bonds has been developed using aluminium reagents in the absence of catalysts.
Nickel(II)-catalyzed carbon-carbon bond formation reaction of functionalized organozinc reagents with aromatic aldehydes
Fu, Ying,Wang, Jin-Xian,Wang, Kehu,Hu, Yulai
experimental part, p. 11124 - 11128 (2009/04/11)
In the presence of a silylating reagent and catalytic amount of Ni(acac)2, organozinc halides reacted with aromatic aldehydes to give the corresponding dialkylation products in good to excellent yields under mild conditions.
Nickel(II)-catalyzed dialkylation of aromatic aldehydes with organozinc reagents
Hu, Yulai,Wang, Jin-Xian,Li, Wenbo
, p. 174 - 175 (2007/10/03)
A novel reaction of the dialkylation of arylaldehydes is provided. The reaction of substituted aromatic aldehyde with organozinc halides in the presence of catalytic amount of Ni(acac)2 and a tertiary amine using a silylating agent to give 1-alkyl-1-arylalkanes in satisfactory yields.
