20229-50-9

Upstream product

• 611-73-4 Benzoylformic acid 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 15206-55-0 methyl 2-oxo-2-phenylacetate 

Downstream Products

• 116841-96-4 (1R,5S,6R)-6-Phenyl-2,7-dioxa-bicyclo[3.2.0]hept-3-ene-6-carboxylic acid (3aR,5R,6S,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester 
• 116909-00-3 (1S,5R,6S)-6-Phenyl-2,7-dioxa-bicyclo[3.2.0]hept-3-ene-6-carboxylic acid (3aR,5R,6S,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester 

Relevant academic research and scientific papers

F--Free Deoxyhydrotrifluoromethylation of α-Keto Esters with Ph3P+CF2CO2-: Synthesis of α-CF3-Substituted Esters

Trifluoromethylated compounds are usually obtained via trifluoromethylation reaction by the use of CF3SiMe3 and NaSO2CF3, Umemoto's and Togni's reagents. Here, an external fluorine anion-free direct deoxyhydrotrifluoromethylation of α-keto esters with a d

Chiral Induction in Photochemical Reactions, IX. - Isoselectivity in the Asymmetric Paterno-Buechi Reaction Using Carbohydrates as Chiral Auxiliaries

The diastereomeric excess obtained in the asymmetric photochemical oxetane formation from the phenylglyoxylates 1a-g and furan (2) depends considerably on both the reaction temperature and the structure of the carbohydrate auxiliary.We observed an isosele