202530-66-3Relevant academic research and scientific papers
Nickel-catalyzed tandem coupling of allyl electrophiles, alkynes, and alkynyltins
Cui, Dong-Mei,Tsuzuki, Takao,Miyake, Kaori,Ikeda, Shin-Ichi,Sato, Yoshiro
, p. 1063 - 1072 (1998)
The nickel-catalyzed intermolecular coupling of allyl acetate or allyl carbonate with alkynes and alkynyltins was carried out in the presence of LiCl to give 3,6-dien-1-yne regio- and stereoselectively. On the other hand, the intramolecular cyclization and coupling of ω-alkynyl electrophiles with alkynyltins gave five-membered cyclic products.
