Tetrahedron p. 1063 - 1072 (1998)
Update date:2022-08-03
Topics:
Cui, Dong-Mei
Tsuzuki, Takao
Miyake, Kaori
Ikeda, Shin-Ichi
Sato, Yoshiro
The nickel-catalyzed intermolecular coupling of allyl acetate or allyl carbonate with alkynes and alkynyltins was carried out in the presence of LiCl to give 3,6-dien-1-yne regio- and stereoselectively. On the other hand, the intramolecular cyclization and coupling of ω-alkynyl electrophiles with alkynyltins gave five-membered cyclic products.
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