202533-34-4Relevant academic research and scientific papers
Successive O-C/O-H and sp3 C-H bond activation of ortho substituents in allyl phenyl ethers and phenols by a ruthenium(0) complex
Hirano, Masafumi,Kurata, Naoki,Marumo, Tsuyoshi,Komiya, Sanshiro
, p. 501 - 503 (1998)
Successive O-C and sp3 C-H bond activation occurs in the reaction of Ru(COD)(COT) (1)/PMe3 with allyl 2,6-xylyl ether to give Ru[OC6H3(o-CH2)(o′-Me)](PMe 3)4 (4). Alternatively, 4 can be obtained by O-H and sp3 C-H bond activation in 2,6-xylenol by 1/PMe3. In both cases, an η3-allyl fragment could be responsible for the sp3 C-H bond activation.
