202596-67-6Relevant articles and documents
Metal-free aza-Claisen type ring expansion of vinyl aziridines: An expeditious synthesis of seven membered N-heterocycles
Singh, Deepak,Ha, Hyun-Joon
supporting information, p. 3093 - 3097 (2019/03/26)
A metal-free approach for the synthesis of 7-membered aza-heterocycles has been developed by the intermolecular [5 + 2] cycloaddition of non-activated vinylaziridines and alkynes. This method has a broad substrate scope under mild reaction conditions to a
Dynamic kinetic asymmetric cycloadditions of isocyanates to vinylaziridines
Trost, Barry M.,Fandrick, Daniel R.
, p. 11836 - 11837 (2007/10/03)
The first examples of the use of racemic vinylaziridines in a Pd-catalyzed dynamic kinetic asymmetric transformation have been examined. Optimization studies of the Pd-catalyzed addition of vinylaziridines to isocyanates revealed that the chiral ligand be
