202869-58-7Relevant academic research and scientific papers
N-TMS-β,β-difluoroenamines: Electrochemical preparation and its transormation
Uneyama, Kenji,Kato, Tsuyoshi
, p. 587 - 590 (1998)
The first preparation of N-trimethylsilylated β,β-difluoroenamines (2) from the trifluoromethyl imines (1) by electrochemical reduction and a preliminary study on alkylation of 2 for the synthesis of difluoromethylene compounds are described.
First synthesis of 3,3-difluoroserine and cysteine derivatives via Mg(0)-promoted selective C-F bond cleavage of trifluoromethylimines
Mae,Amii,Uneyama
, p. 7893 - 7896 (2007/10/03)
3,3-Difluoroserine and cysteine derivatives were synthesized via Mg(0)-promoted defluorination of trifluoromethylimines as a key step, followed by addition of alcohols and sulfenyl chloride, respectively. (C) 2000 Elsevier Science Ltd.
