20291-59-2Relevant academic research and scientific papers
Synthesis and sensorial properties of mercaptoaldehydes
Vermeulen, Catherine,Collin, Sonia
, p. 5654 - 5659 (2007/10/03)
Mercaptoalcohols and mercaptoketones have been described in the past decade as relevant character-impact compounds in various food products. On the other hand, very little is known of mercaptoaldehydes. Only 3-mercapto-2-methylpentanal and 3-mercaptohexan
Thermal Decomposition of 1,2-Oxathiolane in the Gas Phase
Carlsen, Lars,Egsgaard, Helge
, p. 1393 - 1399 (2007/10/02)
The cyclic sulfenic ester 1,2-oxathiolane (1) decomposes thermally (400 - 450 K) exclusively to give acrolein (3) via 3-mercaptopropanal (2) by loss of hydrogen sulfide.Isotopic labelling experiments reveal the presence of a 1,2-oxathiolane-thietane 1-oxide equilibrium (1 4).
