203131-82-2

Upstream product

• 183164-38-7 1-((methylthio)methyl)-1H-benzo[d][1,2,3]triazole 
• 95-14-7 1,2,3-Benzotriazole 

Downstream Products

• 6362-61-4 2-oxo-N,3-diphenylpropanamide 
• 41049-36-9 1-hydroxy-1,3-diphenylacetone 
• 325492-07-7 1-(benzotriazol-1-yl)-2-phenyl-1-methylthio-1-(trimethylsilyl)ethane 
• 203131-98-0 1-(1-Benzotriazol-1-yl-1-methylsulfanyl-2-phenyl-ethyl)-cyclohexanol 

Relevant academic research and scientific papers

Syntheses of Dialkyl and Functionalized Ketones via 1-(Benzotriazol-1-yl)alkyl Methyl Thioethers

Benzotriazol-1-ylmethyl methyl thioether (1), after easy deprotonation by BuLi, reacted with alkyl halides to afford 1-(benzotriazol-1-yl)alkyl methyl thioethers 2 in good yields. The utility of compounds 2 as alkanoyl anion equivalents was demonstrated by the reactions of their anions with alkyl halides, aldehydes, ketones, esters, and phenyl isocyanate: the products were readily hydrolyzed to α-functionalized ketones in dilute aqueous acid.