203190-41-4

Basic information

• Product Name: N-allyl-8-aminomenthol
• Synonyms: N-allyl-8-aminomenthol
• CAS NO: 203190-41-4
• Molecular Weight: 211.348
• Mol File: 203190-41-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N-allyl-8-aminomenthol(CAS DataBase Reference)
• NIST Chemistry Reference: N-allyl-8-aminomenthol(203190-41-4)
• EPA Substance Registry System: N-allyl-8-aminomenthol(203190-41-4)

Safety Data

• Hazardous Substances Data: 203190-41-4(Hazardous Substances Data)

Upstream product

• 115156-56-4 (1R,2S,5R)-5-methyl-2-<1-methyl-1-(benzylamino)ethyl>cyclohexan-1-ol 
• 454251-71-9 (2S,4aS,7R,8aR)-N-allyl-2-hydroxymethyl-4,4,7-trimethyl-octahydro-1,3-benzoxazine 
• 454251-70-8 (2S,4aS,7R,8aR)-2-hydroxymethyl-4,4,7-trimethyl-octahydro-1,3-benzoxazine 
• 55179-51-6 (-)-aminomenthol 
• 7689-50-1 N-benzyl glycine hydrochloride 
• 454251-75-3 (2S,4aS,7R,8aR)-N-allyl-2-formyl-4,4,7-trimethyl-octahydro-1,3-benzoxazine 
• 106-95-6 allyl bromide 

Downstream Products

• 186597-31-9 (3'S)-8-(3'-methylpyrrolidinyl)menthol 
• 186597-30-8 (3'R)-8-(3'-methylpyrrolidinyl)menthol 
• 188644-86-2 N-(8-mentholyl)-(3aR,6R,7aR)-3a,6-epoxy-3a,6,7,7a-tetrahydroisoindoline 
• 188644-85-1 N-(8-mentholyl)-(3aS,6S,7aS)-3a,6-epoxy-3a,6,7,7a-tetrahydroisoindoline 
• 1666-13-3 diphenyl diselenide 
• 235093-81-9 N-allyl-2α-(phenylseleno)methyl-4,4,7α-trimethyl-trans-octahydro-1,3-benzoxazine 
• 203190-42-5 (2S,3S,4aS,7R,8aR)-3-Allyl-2-(2-bromo-phenyl)-4,4,7-trimethyl-octahydro-benzo[e][1,3]oxazine 

Relevant articles and documents

A novel synthesis of enantiopure octahydropyrrolo[3,4-b]pyrroles by intramolecular [3 + 2] dipolar cycloaddition on chiral perhydro-1,3-benzoxazines

(Matrix presented) Condensation of N-substituted glycines with chiral 3-allyl-2-formyl perhydro-1,3-benzoxazines forms an azomethine ylide that cyclizes to give octahydropyrrolo[3,4-b]pyrrole derivatives. The [3 + 2] dipolar cycloadditions are stereoespec

Unexpected stereoselective 6-exo versus 7-endo aryl radical cyclisation controlled by positional isomers in a chiral octahydro-1,3-benzoxazine moiety

Chiral perhydro-1,3-benzoxazines which carry both olefinic and bromo-aromatic substituents undergo stereo- and regio- radical cyclisations mediated by Bu3SnH. Diastereomeric six-membered and seven-membered rings are formed in positional isomers through selective 6-exo and 7-endo attack respectively.