2034-06-2

Basic information

• Product Name: Ph₃GeSPh
• CAS NO: 2034-06-2
• Molecular Weight: 413.079
• Mol File: 2034-06-2.mol

Chemical Properties

• CAS DataBase Reference: Ph₃GeSPh(CAS DataBase Reference)
• NIST Chemistry Reference: Ph₃GeSPh(2034-06-2)
• EPA Substance Registry System: Ph₃GeSPh(2034-06-2)

Safety Data

• Hazardous Substances Data: 2034-06-2(Hazardous Substances Data)

Upstream product

• 1626-24-0 chlorotriphenylgermane 
• 32812-89-8 bis(benzenethiolato)lead(II) 

Downstream Products

• 86774-17-6 W(CO)5((C₆H₅)3GeS(C₆H₅)) 
• 1144112-82-2 [Os3(CO)7(μ-H)(μ-SPh)(μ-bis(diphenylphosphino)methane)(μ3-SC6H4)] 

Relevant articles and documents

Thioether complexes of tungsten hexacarbonyl

The preparation of a series of organic and organometallic thioethers R3MSR' (M = C,Si,Ge, or Sn) is reported.From these, several new compounds of type 1 are synthesized, some of which contain para-substituted aryl functions for R and R'.In hexane solution in the carbonyl streching region of the ir the uv there is evidence for a degree of multiple bonding, at least in the M - S - WW - CO portion of these molecules.Multiple bonding extending into aromatic R or R'is small or non-existent and cannot be assessed precisely because of spontaneous decomposition of the complexes.All the complexes undergo a thermally initiated decomposition, the case of which depends on the nature of R, R', and M.The unusual W(I) thiolate cis-2 is the termal decomposition product.