203569-66-8Relevant articles and documents
Synthesis of 1,3-oxazines and furo[2,3-b]pyrans by reaction of 2-amino-4,5-dihydro-3-furancarbonitriles with dibenzoyldiazomethanes
Yamagata, Kenji,Akizuki, Keiko,Yamazaki, Motoyoshi
, p. 51 - 57 (1998)
2-Amino-4,5-dihydro-3-furancarbonitriles (1) react with a slight excess of dibenzoyldiazomethane in the presence of rhodium(II) acetate to give 1,3-oxazin-4-ones (2). With three equivalents of dibenzoyldiazomethane compounds 1 react to afford furo[2,3-b]pyran-3a-carbonitriles (3). Compound 3a was also obtained by treatment of 2a with two equivalents of dibenzoyldiazomethane. Johann Ambrosius Barth 1998.