59790-95-3Relevant academic research and scientific papers
Controllable one-pot synthesis for scaffold diversity: Via visible-light photoredox-catalyzed Giese reaction and further transformation
Nam, Su Been,Khatun, Nilufa,Kang, Young Woo,Park, Boyoung Y.,Woo, Sang Kook
, p. 2873 - 2876 (2020/03/19)
This study presents a controllable one-pot synthesis for constructing valuable scaffolds (alcohols, 2,3-dihydrofurans, α-cyano-γ-butyrolactones, and γ-butyrolactones) via a visible-light photoredox-catalyzed Giese reaction and further transformation. This
Eosin Y as a Direct Hydrogen-Atom Transfer Photocatalyst for the Functionalization of C?H Bonds
Fan, Xuan-Zi,Rong, Jia-Wei,Wu, Hao-Lin,Zhou, Quan,Deng, Hong-Ping,Da Tan, Jin,Xue, Cheng-Wen,Wu, Li-Zhu,Tao, Hai-Rong,Wu, Jie
supporting information, p. 8514 - 8518 (2018/07/14)
Eosin Y, a well-known economical alternative to metal catalysts in visible-light-driven single-electron transfer-based organic transformations, can behave as an effective direct hydrogen-atom transfer catalyst for C?H activation. Using the alkylation of C?H bonds with electron-deficient alkenes as a model study revealed an extremely broad substrate scope, enabling easy access to a variety of important synthons. This eosin Y-based photocatalytic hydrogen-atom transfer strategy is promising for diverse functionalization of a wide range of native C?H bonds in a green and sustainable manner.
Studies on Heterocyclic Enaminonitriles. VI. Synthesis of 2-Amino-3-cyano-4,5-dihydrofurans
Matsuda, Takumi,Yamagata, Kenji,Tomioka, Yukihiko,Yamazaki, Motoyoshi
, p. 937 - 943 (2007/10/02)
Malononitrile reacts with 2-chloroethanol and 1-chloro-2-propanol (or 2-methyloxirane) in the presence of sodium ethoxide to give 2-amino-3-cyano-4,5-dihydrofuran (Ia) and 2-amino-3-cyano-5-methyl-4,5-dihydrofuran (Ib), respectively.The reaction of malono
