20365-70-2

Upstream product

• 2314-48-9 (S,S)-dimethyl trithiocarbonate 
• 99-91-2 para-chloroacetophenone 
• 75-15-0 carbon disulfide 
• 74-88-4 methyl iodide 

Downstream Products

• 1142124-87-5 3-(4-chlorobenzoyl)-2H-chromene-2-thione 
• 1228956-77-1 3-(4-chlorobenzoyl)-8-methoxy-2H-chromene-2-thione 
• 1621393-89-2 2-[5-(chloromethyl)-1,3-oxathiolan-2-ylidene]-1-(4-chlorophenyl)ethanone 
• 1263317-27-6 (4-chlorophenyl)(3-thioxo-3H-benzo[f]chromen-2-yl)methanone 

Relevant academic research and scientific papers

Half-sandwich titanium complexes with β-oxodithioester ligands

The reaction of CpTiCl3with HLx[HLx= methyl 3-(4′-X-phenyl)-3-hydroxy-2-propenedithioate ligands; X = H(1), Me(2), OMe(3), Cl(4), Br(5)] in the presence of NEt3yielded the corresponding half-sandwich complexes T

Impact of ligand substituents on the crystal structures, optical and conducting properties of phenylmercury(II) β-oxodithioester complexes

New phenylmercury(II) complexes 1–5 with functionalized β-oxodithioester ligands, [PhHg(II) (β-oxodithioester)], β-oxodithioester = methyl-3-hydroxy-3-(4-pyridyl)-2-propenedithioate L1 1, methyl-3-hydroxy-3-(p-chlorophenyl)-2-propenedithioate L2 2, methyl

Z-2-(2-acyl methylene) thiazolidine-4-ketone derivative as well as preparation method and application thereof

The invention relates to the field of chemical synthesis, in particular to Z-2-(2-acyl methylene) thiazolidine-4-ketone derivatives as well as a preparation method and application thereof. The structural formula of the Z-2-(2-acyl methylene) thiazolidine-

Synthesis and characterization of new square planar heteroleptic cationic complexes [Ni(ii) β-oxodithioester-dppe]+; Their use as a catalyst for Chan-Lam coupling

Novel heteroleptic [Ni(ii) β-oxodithioester-dppe]+PF6- complexes (β-oxodithioester = methyl-3-hydroxy-3-benzyl-2-propenedithioate L1 1, methyl-3-hydroxy-3-(p-methoxyphenyl)-2-propenedithioate L2 2, methyl-3-hydroxy-3-(naphthyl)-2-propenedithioate L3 3, methyl-3-hydroxy-3-(p-chlorophenyl)-2-propenedithioate L4 4, methyl-3-hydroxy-3-(p-bromophenyl)-2-propenedithioate L5 5 and methyl-3-hydroxy-3-(p-cyanophenyl)-2-propenedithioate L6 6) have been synthesized and characterized by elemental (C, H, N) analysis, ESI-MS, IR, UV-visible, 1H, 13C{1H}, 31P{1H} and 19F{1H} NMR spectroscopy. The distorted square planar structures of the isomorphous cationic complexes 2, 3, 4 and 5 have been determined by X-ray crystallography. The catalytic activities of 1-6 were investigated for the Chan-Lam coupling reaction involving arylboronic acids and amines to afford N-arylated products in good to excellent yields under mild conditions with 1 mol% catalyst loading. This catalytic protocol offers significant functional group tolerance, and is endowed with a broad substrate scope. This journal is

Cooperative metal-ligand influence on the formation of coordination polymers, and conducting and photophysical properties of Tl(i) β-oxodithioester complexes

Eight novel Tl(i) β-oxodithioester complexes, [TlL]n (1-8), with ligands, L = methyl-3-hydroxy-3-(2-furyl)-2-propenedithioate (L1), methyl-3-hydroxy-3-(2-thienyl)-2-propenedithioate (L2), methyl-3-hydroxy-3-(3-pyridyl)-2-propenedithioate (L3),

Et3N mediated synthesis of polysubstituted thiophenes from α-oxo ketene dithioacetals

In this Letter, an efficient synthetic route to prepare polysubstituted thiophene derivatives was achieved via the Et3N-mediated (Claisen) rearrangement reaction from α-oxo S-methyl-S-propargyl ketenes, which were obtained through alkylation of

An expedient route to highly functionalized 2H-chromene-2-thiones via ring annulation of β-oxodithioesters catalyzed by InCl3 under solvent-free conditions

A convenient and one-pot synthesis of 3-aroyl/heteroaroyl-2H-chromene-2- thiones and benzo[f]2H-chromene-2-thiones has been developed by the condensation of β-oxodithioesters and salicylaldehydes/α-hydroxynaphthaldehydes in the presence of indium trichlor