2037-15-2Relevant academic research and scientific papers
Propane-1,2-diols from dilactides, oligolactides, or poly-L-lactic acid (PLLA): From plastic waste to chiral bulk chemicals
Shuklov, Ivan A.,Dubrovina, Natalia V.,Schulze, Joachim,Tietz, Wolfgang,Kuehlein, Klaus,Boerner, Armin
, p. 957 - 960 (2014)
The preparation of racemic or enantioenriched propane-1,2-diol from dilactides, oligolactides, or poly-L-lactic acid (PLLA) is described. The transformation is carried out as tandem reactions in MeOH, covering hydrolysis and subsequent hydrogenation by using copper chromite as a catalyst. The starting material present undesired side products of the PLLA synthesis or PLLA waste. Copyright
Catalytic Gas-Phase Production of Lactide from Renewable Alkyl Lactates
De Clercq, Rik,Dusselier, Michiel,Makshina, Ekaterina,Sels, Bert F.
supporting information, p. 3074 - 3078 (2018/03/13)
A new route to lactide, which is a key building block of the bioplastic polylactic acid, is proposed involving a continuous catalytic gas-phase transesterification of renewable alkyl lactates in a scalable fixed-bed setup. Supported TiO2/SiO2 catalysts are highly selective to lactide, with only minimal lactide racemization. The solvent-free process allows for easy product separation and recycling of unconverted alkyl lactates and recyclable lactyl intermediates. The catalytic activity of TiO2/SiO2 catalysts was strongly correlated to their optical properties by DR UV/Vis spectroscopy. Catalysts with high band-gap energy of the supported TiO2 phase, indicative of a high surface spreading of isolated Ti centers, show the highest turnover frequency per Ti site.
