2039-96-5Relevant articles and documents
ALUMINIUMALKYLE MIT HETEROATOMEN. XI. UEBER DIE UMSETZUNG VON SCHWEFELTRIOXID MIT TRIS(SILYLALKYL)ALUMINIUM-VERBINDUNGEN ZU SILYLALKANSULFONATEN
Sonnek, Georg,Mueller, Gisela,Baumgarten, Karl-Guenther
, p. 9 - 14 (1980)
Treatment of sulphur trioxide with tris(silylalkyl)aluminium compounds followed by hydrolysis and extraction with ethyl alcohol is a new method for preparation of substituted sodium silylalkane sulphonates.Weak donor-acceptor complexes of the starting compounds react selectively with insertion at the aluminium-carbon bond without cleavage of the silicon-carbon bond.The structure of the silylalkane sulphonates is determined by 1H NMR and IR spectroscopy.