20408-25-7

Upstream product

• 17101-82-5 E-β-bromovinyl phenyl sulfide 
• 35088-66-5 2-bromoethyl phenyl sulfide 
• 52244-26-5 cis-β-Bromovinyl phenyl sulfone 
• 17101-71-2 Z-β-bromovinyl phenyl sulfide 
• 1822-73-7 phenylthioethylene 
• 160661-43-8 1,2-dibromo-1-phenylsulfanyl-ethane 
• 86143-88-6 β,β-dibromovinyl phenyl sulfone 

Downstream Products

• 17101-80-3 1,2,2-Tribrom-1-phenyl-sulfonylethan 
• 33823-34-6 trans-β-Fluorvinylphenylsulfon 
• 121954-76-5 (2,2-Difluoro-ethanesulfonyl)-benzene 
• 67948-56-5 ((Z)-2-Benzenesulfonyl-vinyl)-diethyl-amine 
• 67875-74-5 C₂₀H₃₇N₃O₂PS⁽¹⁺⁾*Br^(1-) 
• 963-16-6 (E)-1,2-bis(phenylsulfonyl)ethylene 
• 190730-66-6 (2S,5S,6S)-5-((E)-2-Benzenesulfonyl-vinyl)-6-[(R)-3-bromo-2-(tert-butyl-dimethyl-silanyloxy)-but-3-enyl]-2-tert-butyl-5-methyl-[1,3]dioxan-4-one 
• 68969-27-7 (E)-1-(phenylsulfonyl)-3,3-dimethylbut-1-ene 
• 108344-86-1 (Z)-1-(phenylsulfonyl)-3,3-dimethylbut-1-ene 
• 71487-61-1 Methyl 2-methyl-4-(phenylsulfonyl)-2(E)-butenoate 
• 75007-20-4 C₁₄H₂₅N₃O₂PS⁽¹⁺⁾*Br^(1-) 
• 74858-07-4 (E)-1-dimethylamino-2-phenylsulfonylethylene 

Relevant academic research and scientific papers

NUCLEOPHILIC REACTION AT A VINYL CENTER. XXII. SYNTHESIS AND NUCLEOPHILIC VINYLIC SUBSTITUTION IN E-β-FLUOROVINYL ARYL SULFONES

The reaction of potassium fluoride with E-β-bromovinyl aryl sulfones in the presence of 18-crown-6-ether leads to a mixture of the sulfones XC6H4SO2CH2CHF2 and E-XC6H4SO2CH=CHF, the ratio of which decreases in the order X=CH3, H, Cl, NO2.The kinetics of n

Reactions of Alkylmercurials with Heteroatom-Centered Acceptor Radicals

The relative reactivities of alkylmercury halides toward PhS., PhSe., or I. decrease drastically from R = tert-butyl to R = sec-alkyl to R = n-butyl, indicative that R. is formed in the rate-determining step in the attack of these radicals upon RHgCl.The alkyl radicals thus formed will enter into chain reactions in which a heteroatom-centered radical (A.) is regenerated from substrates such as RS-SR, ArSe-SeAr, ArTe-TeAr, PhSe-SO2Ar, Cl-SO2Ph; ZCH=CHA (A = Cl, I, SPh, SO2Ph); or PhCCHA (A = I, SPh, SO2Ph). β-Styrenyl (PhCH=CHA, Ph2C=CHA) and β-phenethynyl (PhCCA) systems with A = I, Br, SO2Ph also enter into chain reactions with mercury(II) salts with the ligands PhS, PhSe, PhSO2, or (EtO)2PO.The relative reactivities of a series of reagents toward t-Bu. and of PhCH=CHA, Ph2C=CHA, and PhCCA toward c-C6H11. are reported as well as the regioselectivity of t-Bu. attack observed for 1,2-disubstituted ethylenes (ZCH=CHA) with Z and A from the group Ph, Cl, Br, I, SO2Ph, SPh, Bu3Sn.Reactions of (E)- and (Z)-PhCH=CHI or MeO2CCH=CHI with t-Bu. or c-C6H11. occurred in a regioselective and stereospecific (retention) manner.Reactions of (E)- and (Z)-ClCH=CHCl occurred in a nonstereospecific manner in which the E/Z product ratio increased with the bulk of the attacking radical.A similar effect on the E/Z product ratios was observed for (Z)-MeO2CCH=CHCl.

NUCLEOPHILIC REACTIONS AT A VINYL CENTER. XIII. REACTION OF β,β-DIBROMOVINYL PHENYL SULFONE WITH SODIUM IODIDE AND THE REACTIVITY OF β,β-DIIODOVINYL PHENYL SULFONE

β-Bromo-β-iodovinyl phenyl sulfone and β,β-diiodovinyl phenyl sulfone were obtained by the reaction of β,β-dibromovinyl phenyl sulfone with sodium iodide in acetone.The reactivity of β,β-diiodovinyl phenyl sulfone in reactions with sodium methoxide and thiophenolates was studied.A comparison was made of the relative reactivities of the various β,β-dihalogenovinyl sulfones (Hlg = Cl, Br, I) in nucleophilic vinylic substitution within the scope of the elimination-addition and direct substitution mechanisms.