20442-98-2

Upstream product

• 6310-21-0 2-(1,1-dimethylethyl)-benzenamine 

Downstream Products

• 1914-02-9 3,3-dimethylindoline 
• 87234-77-3 3,3-dimethyl-5-methoxy-indoline 
• 1373752-23-8 (E)-2-(tert-butyl)-4-styrylaniline 
• 1373752-24-9 C₁₈H₂₃N 
• 1373751-85-9 1-azido-2-tert-butyl-4-phenethylbenzene 
• 1373751-86-0 (E)-1-azido-2-tert-butyl-4-styrylbenzene 
• 1373751-89-3 1-azido-4-bromo-2-tert-butylbenzene 
• 1373751-92-8 C₂₃H₂₉NO₂ 
• 1373751-93-9 C₂₃H₂₇NO₂ 
• 1373751-94-0 C₂₁H₂₅NO₂ 
• 1373751-95-1 C₂₃H₂₉NO₄ 
• 1373751-84-8 1-azido-2-tert-butyl-4-methoxybenzene 
• 6310-21-0 2-(1,1-dimethylethyl)-benzenamine 
• 2909-81-1 2-tert-butyl-4-methylaniline 

Relevant academic research and scientific papers

Synergistic combination of visible-light photo-catalytic electron and energy transfer facilitating multicomponent synthesis of β-functionalized α,α-diarylethylamines

A synthetic strategy with the visible-light photo-catalytic synergistic combination of electron and energy transfer processes has been developed. The mild reaction conditions allow the radical-radical cross-coupling phenomenon for the multicomponent synthesis of β-arylsulfonyl(diarylphosphinoyl)-α,α-diarylethyl-amines from readily available arylsulfinic acids (diarylphosphine oxides), 1,1-diarylethylenes and arylazides.

Iron-Catalyzed Intramolecular Aminations of C(sp3)?H Bonds in Alkylaryl Azides

The nucleophilic iron complex Bu4N[Fe(CO)3(NO)] (TBA[Fe]) catalyzes the direct intramolecular amination of unactivated C(sp3)?H bonds in alkylaryl azides, which results in the formation of substituted indoline and tetrahydroquinoline derivatives.

Rh2(II)-catalyzed intramolecular aliphatic C-H bond amination reactions using aryl azides as the N-atom source

Rhodium(II) dicarboxylate complexes were discovered to catalyze the intramolecular amination of unactivated primary, secondary, or tertiary aliphatic C-H bonds using aryl azides as the N-atom precursor. While a strong electron-withdrawing group on the nitrogen atom is typically required to achieve this reaction, we found that both electron-rich and electron-poor aryl azides are efficient sources for the metal nitrene reactive intermediate.