16078-33-4Relevant academic research and scientific papers
Copper-Catalyzed Amination of C(sp3)-H bonds: From Anilides to Indolines
Long, Jinguo,Le, Liyuan,Iwasaki, Takanori,Qiu, Renhua,Kambe, Nobuaki
, p. 482 - 492 (2019/12/24)
Copper-catalyzed oxidative intramolecular cyclization of o-alkylated anilines via cleavage of C(sp3)-H and N-H bonds for the production of indolines is described. This approach provides a straightforward strategy for the synthesis of nitrogen-c
Intramolecular, Site-Selective, Iodine-Mediated, Amination of Unactivated (sp3)C-H Bonds for the Synthesis of Indoline Derivatives
Long, Jinguo,Cao, Xin,Zhu, Longzhi,Qiu, Renhua,Au, Chak-Tong,Yin, Shuang-Feng,Iwasaki, Takanori,Kambe, Nobuaki
supporting information, p. 2793 - 2796 (2017/06/07)
The Iodine-mediated oxidative intramolecular amination of anilines via cleavage of unactivated (sp3)C-H and N-H bonds for the production of indolines is described. This transition-metal-free approach provides a straightforward strategy for prod
Iron-Catalyzed Intramolecular Aminations of C(sp3)?H Bonds in Alkylaryl Azides
Alt, Isabel T.,Guttroff, Claudia,Plietker, Bernd
, p. 10582 - 10586 (2017/08/22)
The nucleophilic iron complex Bu4N[Fe(CO)3(NO)] (TBA[Fe]) catalyzes the direct intramolecular amination of unactivated C(sp3)?H bonds in alkylaryl azides, which results in the formation of substituted indoline and tetrahydroquinoline derivatives.
Cu-Catalyzed Intramolecular Amidation of Unactivated C(sp3)-H Bonds to Synthesize N-Substituted Indolines
Pan, Fei,Wu, Bin,Shi, Zhang-Jie
supporting information, p. 6487 - 6490 (2016/05/02)
A copper-catalyzed intramolecular amidation of unactivated C(sp3)-H bonds to construct indoline derivatives has been developed. Such an amidation proceeded well at primary C-H bonds preferred to secondary C-H bonds. The transformation owned a b
